A Selenium-Based Ionic Liquid as a Recyclable Solvent for the Catalyst-Free Synthesis of 3-Selenylindoles

The ionic liquid 1-butyl-3-methylimidazolium methylselenite, [bmim][SeO(2)(OCH(3))], was successfully used as solvent in the catalyst-free preparation of 3-arylselenylindoles by the reaction of indole with ArSeCl at room temperature. The products were obtained selectively in good yields without the...

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Autores principales: Zimmermann, Everton G., Thurow, Samuel, Freitas, Camilo S., Mendes, Samuel R., Perin, Gelson, Alves, Diego, Jacob, Raquel G., Lenardão, Eder J.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: MDPI 2013
Materias:
Article
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6269994/
https://www.ncbi.nlm.nih.gov/pubmed/23563858
http://dx.doi.org/10.3390/molecules18044081
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author Zimmermann, Everton G.
Thurow, Samuel
Freitas, Camilo S.
Mendes, Samuel R.
Perin, Gelson
Alves, Diego
Jacob, Raquel G.
Lenardão, Eder J.
author_facet Zimmermann, Everton G.
Thurow, Samuel
Freitas, Camilo S.
Mendes, Samuel R.
Perin, Gelson
Alves, Diego
Jacob, Raquel G.
Lenardão, Eder J.
author_sort Zimmermann, Everton G.
collection PubMed
description The ionic liquid 1-butyl-3-methylimidazolium methylselenite, [bmim][SeO(2)(OCH(3))], was successfully used as solvent in the catalyst-free preparation of 3-arylselenylindoles by the reaction of indole with ArSeCl at room temperature. The products were obtained selectively in good yields without the need of any additive and the solvent was easily reused for several cycles with good results.
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spelling pubmed-62699942018-12-14 A Selenium-Based Ionic Liquid as a Recyclable Solvent for the Catalyst-Free Synthesis of 3-Selenylindoles Zimmermann, Everton G. Thurow, Samuel Freitas, Camilo S. Mendes, Samuel R. Perin, Gelson Alves, Diego Jacob, Raquel G. Lenardão, Eder J. Molecules Article The ionic liquid 1-butyl-3-methylimidazolium methylselenite, [bmim][SeO(2)(OCH(3))], was successfully used as solvent in the catalyst-free preparation of 3-arylselenylindoles by the reaction of indole with ArSeCl at room temperature. The products were obtained selectively in good yields without the need of any additive and the solvent was easily reused for several cycles with good results. MDPI 2013-04-05 /pmc/articles/PMC6269994/ /pubmed/23563858 http://dx.doi.org/10.3390/molecules18044081 Text en © 2013 by the authors; licensee MDPI, Basel, Switzerland. This article is an open access article distributed under the terms and conditions of the Creative Commons Attribution license (http://creativecommons.org/licenses/by/3.0/).
spellingShingle Article
Zimmermann, Everton G.
Thurow, Samuel
Freitas, Camilo S.
Mendes, Samuel R.
Perin, Gelson
Alves, Diego
Jacob, Raquel G.
Lenardão, Eder J.
A Selenium-Based Ionic Liquid as a Recyclable Solvent for the Catalyst-Free Synthesis of 3-Selenylindoles
title A Selenium-Based Ionic Liquid as a Recyclable Solvent for the Catalyst-Free Synthesis of 3-Selenylindoles
title_full A Selenium-Based Ionic Liquid as a Recyclable Solvent for the Catalyst-Free Synthesis of 3-Selenylindoles
title_fullStr A Selenium-Based Ionic Liquid as a Recyclable Solvent for the Catalyst-Free Synthesis of 3-Selenylindoles
title_full_unstemmed A Selenium-Based Ionic Liquid as a Recyclable Solvent for the Catalyst-Free Synthesis of 3-Selenylindoles
title_short A Selenium-Based Ionic Liquid as a Recyclable Solvent for the Catalyst-Free Synthesis of 3-Selenylindoles
title_sort selenium-based ionic liquid as a recyclable solvent for the catalyst-free synthesis of 3-selenylindoles
topic Article
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6269994/
https://www.ncbi.nlm.nih.gov/pubmed/23563858
http://dx.doi.org/10.3390/molecules18044081
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