Two New Phragmalin-Type Limonoids from Chukrasia tabularis var. velutina

Two new phragmalin-type limonoids with different structural skeletons, chuktabrin K (1) and tabulalin J (2), were isolated from the stem barks of Chukrasia tabularis var. velutina in the course of our ongoing research work in this area. Compound 1 was a 16-norphragmalin with an enolic alkyl appendag...

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Detalles Bibliográficos
Autores principales: Li, Yi, Luo, Jun, Li, Hui, Kong, Ling-Yi
Formato: Online Artículo Texto
Lenguaje:English
Publicado: MDPI 2012
Materias:
Article
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6270024/
https://www.ncbi.nlm.nih.gov/pubmed/23271471
http://dx.doi.org/10.3390/molecules18010373
Descripción
Sumario:Two new phragmalin-type limonoids with different structural skeletons, chuktabrin K (1) and tabulalin J (2), were isolated from the stem barks of Chukrasia tabularis var. velutina in the course of our ongoing research work in this area. Compound 1 was a 16-norphragmalin with an enolic alkyl appendage at C-15, and the carbonate moiety in 1 was also rare in natural organic molecules. The basic skeleton of compound 2 was a D-ring-opened phragmalin. Their structures were elucidated on HR-ESI-MS, (1)H and (13)C-NMR, HSQC, HMBC, and ROESY experiments.

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