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Theoretical Analysis on the Kinetic Isotope Effects of Bimolecular Nucleophilic Substitution (S(N)2) Reactions and Their Temperature Dependence
Factors affecting the kinetic isotope effects (KIEs) of the gas-phase S(N)2 reactions and their temperature dependence have been analyzed using the ion-molecule collision theory and the transition state theory (TST). The quantum-mechanical tunneling effects were also considered using the canonical v...
Autores principales: | Tsai, Wan-Chen, Hu, Wei-Ping |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
MDPI
2013
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6270110/ https://www.ncbi.nlm.nih.gov/pubmed/23612475 http://dx.doi.org/10.3390/molecules18044816 |
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