A Series of Asymmetrical Phthalocyanines: Synthesis and Near Infrared Properties

We report here the preparation of asymmetrical phthalocyanine dimers 1a–3a, which are endowed with novel charge transfer bands at 1,151–1,154 nm and strong NIR luminescences at 840–860 nm and 1,600–1,650 nm. Through H-bonding interaction, 1a–3a are inclined to self-assemble into hexrod nanotubes at...

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Detalles Bibliográficos
Autores principales: Huang, Guoqing, Li, Jianxi, Cong, Fangdi, Li, Chao, Chu, Xixi, Meng, Yanyan, Du, Guotong, Du, Xiguang
Formato: Online Artículo Texto
Lenguaje:English
Publicado: MDPI 2013
Materias:
Communication
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6270185/
https://www.ncbi.nlm.nih.gov/pubmed/23603946
http://dx.doi.org/10.3390/molecules18044628
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author Huang, Guoqing
Li, Jianxi
Cong, Fangdi
Li, Chao
Chu, Xixi
Meng, Yanyan
Du, Guotong
Du, Xiguang
author_facet Huang, Guoqing
Li, Jianxi
Cong, Fangdi
Li, Chao
Chu, Xixi
Meng, Yanyan
Du, Guotong
Du, Xiguang
author_sort Huang, Guoqing
collection PubMed
description We report here the preparation of asymmetrical phthalocyanine dimers 1a–3a, which are endowed with novel charge transfer bands at 1,151–1,154 nm and strong NIR luminescences at 840–860 nm and 1,600–1,650 nm. Through H-bonding interaction, 1a–3a are inclined to self-assemble into hexrod nanotubes at the interface of CHCl(3) and CH(3)OH. Our results provide further insights into the interaction in molecular dimers, and suggest that 1a–3a have potential application in magnets and supramolecular architectures.
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spelling pubmed-62701852018-12-14 A Series of Asymmetrical Phthalocyanines: Synthesis and Near Infrared Properties Huang, Guoqing Li, Jianxi Cong, Fangdi Li, Chao Chu, Xixi Meng, Yanyan Du, Guotong Du, Xiguang Molecules Communication We report here the preparation of asymmetrical phthalocyanine dimers 1a–3a, which are endowed with novel charge transfer bands at 1,151–1,154 nm and strong NIR luminescences at 840–860 nm and 1,600–1,650 nm. Through H-bonding interaction, 1a–3a are inclined to self-assemble into hexrod nanotubes at the interface of CHCl(3) and CH(3)OH. Our results provide further insights into the interaction in molecular dimers, and suggest that 1a–3a have potential application in magnets and supramolecular architectures. MDPI 2013-04-19 /pmc/articles/PMC6270185/ /pubmed/23603946 http://dx.doi.org/10.3390/molecules18044628 Text en © 2013 by the authors; licensee MDPI, Basel, Switzerland. This article is an open access article distributed under the terms and conditions of the Creative Commons Attribution license (http://creativecommons.org/licenses/by/3.0/).
spellingShingle Communication
Huang, Guoqing
Li, Jianxi
Cong, Fangdi
Li, Chao
Chu, Xixi
Meng, Yanyan
Du, Guotong
Du, Xiguang
A Series of Asymmetrical Phthalocyanines: Synthesis and Near Infrared Properties
title A Series of Asymmetrical Phthalocyanines: Synthesis and Near Infrared Properties
title_full A Series of Asymmetrical Phthalocyanines: Synthesis and Near Infrared Properties
title_fullStr A Series of Asymmetrical Phthalocyanines: Synthesis and Near Infrared Properties
title_full_unstemmed A Series of Asymmetrical Phthalocyanines: Synthesis and Near Infrared Properties
title_short A Series of Asymmetrical Phthalocyanines: Synthesis and Near Infrared Properties
title_sort series of asymmetrical phthalocyanines: synthesis and near infrared properties
topic Communication
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6270185/
https://www.ncbi.nlm.nih.gov/pubmed/23603946
http://dx.doi.org/10.3390/molecules18044628
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