Probing Ionic Liquid Aqueous Solutions Using Temperature of Maximum Density Isotope Effects

This work is a new development of an extensive research program that is investigating for the first time shifts in the temperature of maximum density (TMD) of aqueous solutions caused by ionic liquid solutes. In the present case we have compared the shifts caused by three ionic liquid solutes with a...

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Detalles Bibliográficos
Autores principales: Tariq, Mohammad, Esperança, José M. S. S., Rebelo, Luís P. N., Lopes, José N. Canongia
Formato: Online Artículo Texto
Lenguaje:English
Publicado: MDPI 2013
Materias:
Article
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6270296/
https://www.ncbi.nlm.nih.gov/pubmed/23529030
http://dx.doi.org/10.3390/molecules18043703
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author Tariq, Mohammad
Esperança, José M. S. S.
Rebelo, Luís P. N.
Lopes, José N. Canongia
author_facet Tariq, Mohammad
Esperança, José M. S. S.
Rebelo, Luís P. N.
Lopes, José N. Canongia
author_sort Tariq, Mohammad
collection PubMed
description This work is a new development of an extensive research program that is investigating for the first time shifts in the temperature of maximum density (TMD) of aqueous solutions caused by ionic liquid solutes. In the present case we have compared the shifts caused by three ionic liquid solutes with a common cation—1-ethyl-3-methylimidazolium coupled with acetate, ethylsulfate and tetracyanoborate anions—in normal and deuterated water solutions. The observed differences are discussed in terms of the nature of the corresponding anion-water interactions.
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spelling pubmed-62702962018-12-14 Probing Ionic Liquid Aqueous Solutions Using Temperature of Maximum Density Isotope Effects Tariq, Mohammad Esperança, José M. S. S. Rebelo, Luís P. N. Lopes, José N. Canongia Molecules Article This work is a new development of an extensive research program that is investigating for the first time shifts in the temperature of maximum density (TMD) of aqueous solutions caused by ionic liquid solutes. In the present case we have compared the shifts caused by three ionic liquid solutes with a common cation—1-ethyl-3-methylimidazolium coupled with acetate, ethylsulfate and tetracyanoborate anions—in normal and deuterated water solutions. The observed differences are discussed in terms of the nature of the corresponding anion-water interactions. MDPI 2013-03-25 /pmc/articles/PMC6270296/ /pubmed/23529030 http://dx.doi.org/10.3390/molecules18043703 Text en © 2013 by the authors; licensee MDPI, Basel, Switzerland. http://creativecommons.org/licenses/by/3.0/ This article is an open access article distributed under the terms and conditions of the Creative Commons Attribution license (http://creativecommons.org/licenses/by/3.0/).
spellingShingle Article
Tariq, Mohammad
Esperança, José M. S. S.
Rebelo, Luís P. N.
Lopes, José N. Canongia
Probing Ionic Liquid Aqueous Solutions Using Temperature of Maximum Density Isotope Effects
title Probing Ionic Liquid Aqueous Solutions Using Temperature of Maximum Density Isotope Effects
title_full Probing Ionic Liquid Aqueous Solutions Using Temperature of Maximum Density Isotope Effects
title_fullStr Probing Ionic Liquid Aqueous Solutions Using Temperature of Maximum Density Isotope Effects
title_full_unstemmed Probing Ionic Liquid Aqueous Solutions Using Temperature of Maximum Density Isotope Effects
title_short Probing Ionic Liquid Aqueous Solutions Using Temperature of Maximum Density Isotope Effects
title_sort probing ionic liquid aqueous solutions using temperature of maximum density isotope effects
topic Article
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6270296/
https://www.ncbi.nlm.nih.gov/pubmed/23529030
http://dx.doi.org/10.3390/molecules18043703
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