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Click Reactions as a Key Step for an Efficient and Selective Synthesis of d-Xylose-Based ILs

d-Xylose-based ionic liquids have been prepared from d-xylose following a five steps reaction sequence, the key step being a click cycloaddition. These ionic liquids (ILs) have been characterized through classical analytical methods (IR, NMR, mass spectroscopy, elemental analysis) and their stabilit...

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Detalles Bibliográficos
Autores principales: Ferlin, Nadège, Gatard, Sylvain, Van Nhien, Albert Nguyen, Courty, Matthieu, Bouquillon, Sandrine
Formato: Online Artículo Texto
Lenguaje:English
Publicado: MDPI 2013
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6270402/
https://www.ncbi.nlm.nih.gov/pubmed/24048284
http://dx.doi.org/10.3390/molecules180911512
Descripción
Sumario:d-Xylose-based ionic liquids have been prepared from d-xylose following a five steps reaction sequence, the key step being a click cycloaddition. These ionic liquids (ILs) have been characterized through classical analytical methods (IR, NMR, mass spectroscopy, elemental analysis) and their stability constants, Tg and Tdec, were also determined. Considering their properties and their hydrophilicity, these compounds could be alternative solvents for chemical applications under mild conditions.