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Synthesis of α-O- and α-S-Glycosphingolipids Related to Sphingomonous cell Wall Antigens Using Anomerisation
Analogues of glycolipids from Spingomonadacaece with O- and S- and SO(2)-linkages have been prepared using chelation induced anomerisation promoted by TiCl(4). Included are examples of the anomerisation of intermediates with O- and S-glycosidic linkages as well as isomerisation of β-thioglycuronic a...
| Autores principales: | , , |
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| Formato: | Online Artículo Texto |
| Lenguaje: | English |
| Publicado: |
MDPI
2013
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| Materias: | |
| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6270446/ https://www.ncbi.nlm.nih.gov/pubmed/24036511 http://dx.doi.org/10.3390/molecules180911198 |