An Efficient Microwave-Assisted Suzuki Reaction using a New Pyridine-Pyrazole/Pd(II) Species as Catalyst in Aqueous Media

A new pyridine-pyrazole N–N ligand has been conveniently synthesized and characterized by (1)H-, (13)C-NMR, IR spectroscopies, HRMS and X-ray single-crystal crystallography analyses. The ligand adds to palladium(II) under basic conditions to give high yields of an air-stable and water-soluble comple...

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Detalles Bibliográficos
Autores principales: Shen, Liqun, Huang, Suyu, Nie, Yuanmei, Lei, Fuhou
Formato: Online Artículo Texto
Lenguaje:English
Publicado: MDPI 2013
Materias:
Article
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6270469/
https://www.ncbi.nlm.nih.gov/pubmed/23353128
http://dx.doi.org/10.3390/molecules18021602
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author Shen, Liqun
Huang, Suyu
Nie, Yuanmei
Lei, Fuhou
author_facet Shen, Liqun
Huang, Suyu
Nie, Yuanmei
Lei, Fuhou
author_sort Shen, Liqun
collection PubMed
description A new pyridine-pyrazole N–N ligand has been conveniently synthesized and characterized by (1)H-, (13)C-NMR, IR spectroscopies, HRMS and X-ray single-crystal crystallography analyses. The ligand adds to palladium(II) under basic conditions to give high yields of an air-stable and water-soluble complex that was fully characterized by NMR and HRMS. The complex was investigated as a catalyst for the Suzuki reaction in aqueous media under microwave irradiation. The compound proved to be an effective catalyst.
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spelling pubmed-62704692018-12-14 An Efficient Microwave-Assisted Suzuki Reaction using a New Pyridine-Pyrazole/Pd(II) Species as Catalyst in Aqueous Media Shen, Liqun Huang, Suyu Nie, Yuanmei Lei, Fuhou Molecules Article A new pyridine-pyrazole N–N ligand has been conveniently synthesized and characterized by (1)H-, (13)C-NMR, IR spectroscopies, HRMS and X-ray single-crystal crystallography analyses. The ligand adds to palladium(II) under basic conditions to give high yields of an air-stable and water-soluble complex that was fully characterized by NMR and HRMS. The complex was investigated as a catalyst for the Suzuki reaction in aqueous media under microwave irradiation. The compound proved to be an effective catalyst. MDPI 2013-01-25 /pmc/articles/PMC6270469/ /pubmed/23353128 http://dx.doi.org/10.3390/molecules18021602 Text en © 2013 by the authors; licensee MDPI, Basel, Switzerland. http://creativecommons.org/licenses/by/3.0/ This article is an open access article distributed under the terms and conditions of the Creative Commons Attribution license (http://creativecommons.org/licenses/by/3.0/).
spellingShingle Article
Shen, Liqun
Huang, Suyu
Nie, Yuanmei
Lei, Fuhou
An Efficient Microwave-Assisted Suzuki Reaction using a New Pyridine-Pyrazole/Pd(II) Species as Catalyst in Aqueous Media
title An Efficient Microwave-Assisted Suzuki Reaction using a New Pyridine-Pyrazole/Pd(II) Species as Catalyst in Aqueous Media
title_full An Efficient Microwave-Assisted Suzuki Reaction using a New Pyridine-Pyrazole/Pd(II) Species as Catalyst in Aqueous Media
title_fullStr An Efficient Microwave-Assisted Suzuki Reaction using a New Pyridine-Pyrazole/Pd(II) Species as Catalyst in Aqueous Media
title_full_unstemmed An Efficient Microwave-Assisted Suzuki Reaction using a New Pyridine-Pyrazole/Pd(II) Species as Catalyst in Aqueous Media
title_short An Efficient Microwave-Assisted Suzuki Reaction using a New Pyridine-Pyrazole/Pd(II) Species as Catalyst in Aqueous Media
title_sort efficient microwave-assisted suzuki reaction using a new pyridine-pyrazole/pd(ii) species as catalyst in aqueous media
topic Article
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6270469/
https://www.ncbi.nlm.nih.gov/pubmed/23353128
http://dx.doi.org/10.3390/molecules18021602
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