Cross-Coupling Reaction with Lithium Methyltriolborate

We newly developed lithium methyltriolborate as an air-stable white solid that is convenient to handle. The good performance of this triolborate for metal-catalyzed bond-forming reactions was demonstrated in palladium-catalyzed cross-coupling reactions with haloarenes. Cross-coupling reaction of [Me...

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Detalles Bibliográficos
Autores principales: Yamamoto, Yasunori, Ikizakura, Kazuya, Ito, Hajime, Miyaura, Norio
Formato: Online Artículo Texto
Lenguaje:English
Publicado: MDPI 2012
Materias:
Article
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6270471/
https://www.ncbi.nlm.nih.gov/pubmed/23275051
http://dx.doi.org/10.3390/molecules18010430
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author Yamamoto, Yasunori
Ikizakura, Kazuya
Ito, Hajime
Miyaura, Norio
author_facet Yamamoto, Yasunori
Ikizakura, Kazuya
Ito, Hajime
Miyaura, Norio
author_sort Yamamoto, Yasunori
collection PubMed
description We newly developed lithium methyltriolborate as an air-stable white solid that is convenient to handle. The good performance of this triolborate for metal-catalyzed bond-forming reactions was demonstrated in palladium-catalyzed cross-coupling reactions with haloarenes. Cross-coupling reaction of [MeB(OCH(2))(3)CCH(3)]Li with aryl halides occurred in the presence of Pd(OAc)(2)/RuPhos complex in refluxing MeOH/H(2)O and the absence of bases.
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spelling pubmed-62704712018-12-14 Cross-Coupling Reaction with Lithium Methyltriolborate Yamamoto, Yasunori Ikizakura, Kazuya Ito, Hajime Miyaura, Norio Molecules Article We newly developed lithium methyltriolborate as an air-stable white solid that is convenient to handle. The good performance of this triolborate for metal-catalyzed bond-forming reactions was demonstrated in palladium-catalyzed cross-coupling reactions with haloarenes. Cross-coupling reaction of [MeB(OCH(2))(3)CCH(3)]Li with aryl halides occurred in the presence of Pd(OAc)(2)/RuPhos complex in refluxing MeOH/H(2)O and the absence of bases. MDPI 2012-12-28 /pmc/articles/PMC6270471/ /pubmed/23275051 http://dx.doi.org/10.3390/molecules18010430 Text en © 2013 by the authors; licensee MDPI, Basel, Switzerland. This article is an open access article distributed under the terms and conditions of the Creative Commons Attribution license (http://creativecommons.org/licenses/by/3.0/).
spellingShingle Article
Yamamoto, Yasunori
Ikizakura, Kazuya
Ito, Hajime
Miyaura, Norio
Cross-Coupling Reaction with Lithium Methyltriolborate
title Cross-Coupling Reaction with Lithium Methyltriolborate
title_full Cross-Coupling Reaction with Lithium Methyltriolborate
title_fullStr Cross-Coupling Reaction with Lithium Methyltriolborate
title_full_unstemmed Cross-Coupling Reaction with Lithium Methyltriolborate
title_short Cross-Coupling Reaction with Lithium Methyltriolborate
title_sort cross-coupling reaction with lithium methyltriolborate
topic Article
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6270471/
https://www.ncbi.nlm.nih.gov/pubmed/23275051
http://dx.doi.org/10.3390/molecules18010430
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AT ikizakurakazuya crosscouplingreactionwithlithiummethyltriolborate
AT itohajime crosscouplingreactionwithlithiummethyltriolborate
AT miyauranorio crosscouplingreactionwithlithiummethyltriolborate

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