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Exploring the C-X…π Halogen Bonding Motif: An Infrared and Raman Study of the Complexes of CF(3)X (X = Cl, Br and I) with the Aromatic Model Compounds Benzene and Toluene

The formation of halogen bonded complexes formed between the trifluorohalomethanes CF(3)Cl, CF(3)Br and CF(3)I and the Lewis bases benzene and toluene at temperatures below 150K was investigated using FTIR and Raman spectroscopy. Experiments using liquid krypton as solvent show that for both CF(3)Br...

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Detalles Bibliográficos
Autores principales: Nagels, Nick, Hauchecorne, Dieter, Herrebout, Wouter A.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: MDPI 2013
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6270472/
https://www.ncbi.nlm.nih.gov/pubmed/23752468
http://dx.doi.org/10.3390/molecules18066829