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Exploring the C-X…π Halogen Bonding Motif: An Infrared and Raman Study of the Complexes of CF(3)X (X = Cl, Br and I) with the Aromatic Model Compounds Benzene and Toluene
The formation of halogen bonded complexes formed between the trifluorohalomethanes CF(3)Cl, CF(3)Br and CF(3)I and the Lewis bases benzene and toluene at temperatures below 150K was investigated using FTIR and Raman spectroscopy. Experiments using liquid krypton as solvent show that for both CF(3)Br...
Autores principales: | , , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
MDPI
2013
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6270472/ https://www.ncbi.nlm.nih.gov/pubmed/23752468 http://dx.doi.org/10.3390/molecules18066829 |