Repetitive Two-Step Method for o,o,p- and o,p-Oligophenylene Synthesis through Pd-Catalyzed Cross-Coupling of Hydroxyterphenylboronic Acid

A repetitive two-step method involving the Pd-catalyzed Suzuki-Miyaura coupling of hydroxyterphenylboronic acid and the subsequent nonaflation of the hydroxy group has been developed for the synthesis of oligophenylenes. This method readily afforded o,o,p- and o,p-oligophenylenes with defined chain...

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Autores principales: Yamaguchi, Miyuki, Kimura, Takeshi, Shinohara, Naomi, Manabe, Kei
Formato: Online Artículo Texto
Lenguaje:English
Publicado: MDPI 2013
Materias:
Article
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6270598/
https://www.ncbi.nlm.nih.gov/pubmed/24335574
http://dx.doi.org/10.3390/molecules181215207
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author Yamaguchi, Miyuki
Kimura, Takeshi
Shinohara, Naomi
Manabe, Kei
author_facet Yamaguchi, Miyuki
Kimura, Takeshi
Shinohara, Naomi
Manabe, Kei
author_sort Yamaguchi, Miyuki
collection PubMed
description A repetitive two-step method involving the Pd-catalyzed Suzuki-Miyaura coupling of hydroxyterphenylboronic acid and the subsequent nonaflation of the hydroxy group has been developed for the synthesis of oligophenylenes. This method readily afforded o,o,p- and o,p-oligophenylenes with defined chain lengths. X-ray crystallography was employed to obtain the structure of the o,p-oligophenylene 9-mer.
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spelling pubmed-62705982018-12-20 Repetitive Two-Step Method for o,o,p- and o,p-Oligophenylene Synthesis through Pd-Catalyzed Cross-Coupling of Hydroxyterphenylboronic Acid Yamaguchi, Miyuki Kimura, Takeshi Shinohara, Naomi Manabe, Kei Molecules Article A repetitive two-step method involving the Pd-catalyzed Suzuki-Miyaura coupling of hydroxyterphenylboronic acid and the subsequent nonaflation of the hydroxy group has been developed for the synthesis of oligophenylenes. This method readily afforded o,o,p- and o,p-oligophenylenes with defined chain lengths. X-ray crystallography was employed to obtain the structure of the o,p-oligophenylene 9-mer. MDPI 2013-12-10 /pmc/articles/PMC6270598/ /pubmed/24335574 http://dx.doi.org/10.3390/molecules181215207 Text en © 2013 by the authors; licensee MDPI, Basel, Switzerland. http://creativecommons.org/licenses/by/3.0/ This article is an open access article distributed under the terms and conditions of the Creative Commons Attribution license (http://creativecommons.org/licenses/by/3.0/).
spellingShingle Article
Yamaguchi, Miyuki
Kimura, Takeshi
Shinohara, Naomi
Manabe, Kei
Repetitive Two-Step Method for o,o,p- and o,p-Oligophenylene Synthesis through Pd-Catalyzed Cross-Coupling of Hydroxyterphenylboronic Acid
title Repetitive Two-Step Method for o,o,p- and o,p-Oligophenylene Synthesis through Pd-Catalyzed Cross-Coupling of Hydroxyterphenylboronic Acid
title_full Repetitive Two-Step Method for o,o,p- and o,p-Oligophenylene Synthesis through Pd-Catalyzed Cross-Coupling of Hydroxyterphenylboronic Acid
title_fullStr Repetitive Two-Step Method for o,o,p- and o,p-Oligophenylene Synthesis through Pd-Catalyzed Cross-Coupling of Hydroxyterphenylboronic Acid
title_full_unstemmed Repetitive Two-Step Method for o,o,p- and o,p-Oligophenylene Synthesis through Pd-Catalyzed Cross-Coupling of Hydroxyterphenylboronic Acid
title_short Repetitive Two-Step Method for o,o,p- and o,p-Oligophenylene Synthesis through Pd-Catalyzed Cross-Coupling of Hydroxyterphenylboronic Acid
title_sort repetitive two-step method for o,o,p- and o,p-oligophenylene synthesis through pd-catalyzed cross-coupling of hydroxyterphenylboronic acid
topic Article
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6270598/
https://www.ncbi.nlm.nih.gov/pubmed/24335574
http://dx.doi.org/10.3390/molecules181215207
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