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A Highly Efficient Regioselective Addition of Acetylides to Enediones Based on Steric Effects

A simple and efficient strategy for the synthesis of 1-ethynylcyclohex-2-enol derivatives was developed utilizing regioselective addition of acetylides to enediones based on steric effects. Further investigation of the substrate scope of enediones indicated that all the addition reactions ocurred in...

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Detalles Bibliográficos
Autores principales: Han, Xiaoqiang, Wan, Chuan, Yang, Dongyan, Yuan, Xiaoyong, Du, Shijie, Xiao, Yumei, Qin, Zhaohai
Formato: Online Artículo Texto
Lenguaje:English
Publicado: MDPI 2013
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6270633/
https://www.ncbi.nlm.nih.gov/pubmed/24005970
http://dx.doi.org/10.3390/molecules180910776