A Simple Hydrophilic Palladium(II) Complex as a Highly Efficient Catalyst for Room Temperature Aerobic Suzuki Coupling Reactions in Aqueous Media

A study on room temperature Suzuki cross-coupling in an aqueous medium was carried out using a simple hydrophilic palladium (II) complex, trans-PdCl(2)(NH(2)CH(2)COOH)(2) as catalyst in the presence of K(2)CO(3) in air. This approach with a comparatively inexpensive and hydrophilic catalyst, mild re...

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Detalles Bibliográficos
Autores principales: Guo, Mengping, Liu, Shiwen, Zhou, Xiuling, Lv, Meiyun, Chen, Sanbao, Xiao, Daoan
Formato: Online Artículo Texto
Lenguaje:English
Publicado: MDPI 2014
Materias:
Communication
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6270763/
https://www.ncbi.nlm.nih.gov/pubmed/24853715
http://dx.doi.org/10.3390/molecules19056524
Descripción
Sumario:A study on room temperature Suzuki cross-coupling in an aqueous medium was carried out using a simple hydrophilic palladium (II) complex, trans-PdCl(2)(NH(2)CH(2)COOH)(2) as catalyst in the presence of K(2)CO(3) in air. This approach with a comparatively inexpensive and hydrophilic catalyst, mild reaction condition and aqueous media exhibits excellent catalytic activity towards the Suzuki coupling of aryl bromides and arylboronic acids, and good yields were obtained in the Suzuki coupling of activated aryl chlorides.

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