A Simple Hydrophilic Palladium(II) Complex as a Highly Efficient Catalyst for Room Temperature Aerobic Suzuki Coupling Reactions in Aqueous Media

A study on room temperature Suzuki cross-coupling in an aqueous medium was carried out using a simple hydrophilic palladium (II) complex, trans-PdCl(2)(NH(2)CH(2)COOH)(2) as catalyst in the presence of K(2)CO(3) in air. This approach with a comparatively inexpensive and hydrophilic catalyst, mild re...

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Detalles Bibliográficos
Autores principales: Guo, Mengping, Liu, Shiwen, Zhou, Xiuling, Lv, Meiyun, Chen, Sanbao, Xiao, Daoan
Formato: Online Artículo Texto
Lenguaje:English
Publicado: MDPI 2014
Materias:
Communication
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6270763/
https://www.ncbi.nlm.nih.gov/pubmed/24853715
http://dx.doi.org/10.3390/molecules19056524
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author Guo, Mengping
Liu, Shiwen
Zhou, Xiuling
Lv, Meiyun
Chen, Sanbao
Xiao, Daoan
author_facet Guo, Mengping
Liu, Shiwen
Zhou, Xiuling
Lv, Meiyun
Chen, Sanbao
Xiao, Daoan
author_sort Guo, Mengping
collection PubMed
description A study on room temperature Suzuki cross-coupling in an aqueous medium was carried out using a simple hydrophilic palladium (II) complex, trans-PdCl(2)(NH(2)CH(2)COOH)(2) as catalyst in the presence of K(2)CO(3) in air. This approach with a comparatively inexpensive and hydrophilic catalyst, mild reaction condition and aqueous media exhibits excellent catalytic activity towards the Suzuki coupling of aryl bromides and arylboronic acids, and good yields were obtained in the Suzuki coupling of activated aryl chlorides.
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spelling pubmed-62707632018-12-21 A Simple Hydrophilic Palladium(II) Complex as a Highly Efficient Catalyst for Room Temperature Aerobic Suzuki Coupling Reactions in Aqueous Media Guo, Mengping Liu, Shiwen Zhou, Xiuling Lv, Meiyun Chen, Sanbao Xiao, Daoan Molecules Communication A study on room temperature Suzuki cross-coupling in an aqueous medium was carried out using a simple hydrophilic palladium (II) complex, trans-PdCl(2)(NH(2)CH(2)COOH)(2) as catalyst in the presence of K(2)CO(3) in air. This approach with a comparatively inexpensive and hydrophilic catalyst, mild reaction condition and aqueous media exhibits excellent catalytic activity towards the Suzuki coupling of aryl bromides and arylboronic acids, and good yields were obtained in the Suzuki coupling of activated aryl chlorides. MDPI 2014-05-21 /pmc/articles/PMC6270763/ /pubmed/24853715 http://dx.doi.org/10.3390/molecules19056524 Text en © 2014 by the authors. Licensee MDPI, Basel, Switzerland. This article is an open access article distributed under the terms and conditions of the Creative Commons Attribution license (http://creativecommons.org/licenses/by/3.0/).
spellingShingle Communication
Guo, Mengping
Liu, Shiwen
Zhou, Xiuling
Lv, Meiyun
Chen, Sanbao
Xiao, Daoan
A Simple Hydrophilic Palladium(II) Complex as a Highly Efficient Catalyst for Room Temperature Aerobic Suzuki Coupling Reactions in Aqueous Media
title A Simple Hydrophilic Palladium(II) Complex as a Highly Efficient Catalyst for Room Temperature Aerobic Suzuki Coupling Reactions in Aqueous Media
title_full A Simple Hydrophilic Palladium(II) Complex as a Highly Efficient Catalyst for Room Temperature Aerobic Suzuki Coupling Reactions in Aqueous Media
title_fullStr A Simple Hydrophilic Palladium(II) Complex as a Highly Efficient Catalyst for Room Temperature Aerobic Suzuki Coupling Reactions in Aqueous Media
title_full_unstemmed A Simple Hydrophilic Palladium(II) Complex as a Highly Efficient Catalyst for Room Temperature Aerobic Suzuki Coupling Reactions in Aqueous Media
title_short A Simple Hydrophilic Palladium(II) Complex as a Highly Efficient Catalyst for Room Temperature Aerobic Suzuki Coupling Reactions in Aqueous Media
title_sort simple hydrophilic palladium(ii) complex as a highly efficient catalyst for room temperature aerobic suzuki coupling reactions in aqueous media
topic Communication
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6270763/
https://www.ncbi.nlm.nih.gov/pubmed/24853715
http://dx.doi.org/10.3390/molecules19056524
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