Two New Secondary Metabolites from Xylaria sp. cfcc 87468

A new isocoumarin glycoside, 3R-(+)-5-O-[6'-O-acetyl]-α-d-glucopyranosyl-5-hydroxymellein (1), and a new phenylethanol glycoside, (−)-phenylethyl-8-O-α-l-rhamno-pyranoside (2), were isolated from the ethyl acetate extract of the fungus Xylaria sp. cfcc 87468, together with five known steroids,...

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Detalles Bibliográficos
Autores principales: Wang, Fuqian, Han, Shishi, Hu, Song, Xue, Yongbo, Wang, Jianping, Xu, Hongfeng, Chen, Lu, Zhang, Geng, Zhang, Yonghui
Formato: Online Artículo Texto
Lenguaje:English
Publicado: MDPI 2014
Materias:
Article
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6270958/
https://www.ncbi.nlm.nih.gov/pubmed/24448065
http://dx.doi.org/10.3390/molecules19011250
Descripción
Sumario:A new isocoumarin glycoside, 3R-(+)-5-O-[6'-O-acetyl]-α-d-glucopyranosyl-5-hydroxymellein (1), and a new phenylethanol glycoside, (−)-phenylethyl-8-O-α-l-rhamno-pyranoside (2), were isolated from the ethyl acetate extract of the fungus Xylaria sp. cfcc 87468, together with five known steroids, β-sitosterol (3), stigmast-4-en-3-one (4), ergosterol (5), (22E)-cholesta-4,6,8(14),22-tetraen-3-one (6), and 4α-methyl- ergosta-8(14),24(28)-dien-3β-ol (7). The structures of compounds 1 and 2 were elucidated by MS, extensive 1D and 2D NMR spectroscopy, and the circular dichroism (CD) spectroscopy.

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