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Redox-Dependent Conformational Switching of Diphenylacetylenes

Herein we describe the design and synthesis of a redox-dependent single-molecule switch. Appending a ferrocene unit to a diphenylacetylene scaffold gives a redox-sensitive handle, which undergoes reversible one-electron oxidation, as demonstrated by cyclic voltammetry analysis. (1)H-NMR spectroscopy...

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Detalles Bibliográficos
Autores principales:	Jones, Ian M., Knipe, Peter C., Michaelos, Thoe, Thompson, Sam, Hamilton, Andrew D.
Formato:	Online Artículo Texto
Lenguaje:	English
Publicado:	MDPI 2014
Materias:	Article
Acceso en línea:	https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6271015/ https://www.ncbi.nlm.nih.gov/pubmed/25090120 http://dx.doi.org/10.3390/molecules190811316

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