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NMR Structural Study of the Prototropic Equilibrium in Solution of Schiff Bases as Model Compounds
An NMR titration method has been used to simultaneously measure the acid dissociation constant (pK(a)) and the intramolecular NHO prototropic constant ΔK(NHO) on a set of Schiff bases. The model compounds were synthesized from benzylamine and substituted ortho-hydroxyaldehydes, appropriately substit...
Autores principales: | Ortegón-Reyna, David, Garcías-Morales, Cesar, Padilla-Martínez, Itzia, García-Báez, Efren, Aríza-Castolo, Armando, Peraza-Campos, Ana, Martínez-Martínez, Francisco |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
MDPI
2013
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6271073/ https://www.ncbi.nlm.nih.gov/pubmed/24384925 http://dx.doi.org/10.3390/molecules19010459 |
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