An Unusual Conversion of Paramagnetic [3-Cl-3,3,8-{Ph(2)P(CH(2))(n)PPh-µ-([Image: see text] H(8)] (n = 3 and 4) to Form the First 18-Electron P-Phenylene ortho-Cycloboronated closo-Ruthenacarboranes with a Dioxygen Ligand

Treatment of [3-Cl-3,3,8-[Ph(2)P(CH(2))(n)PPh-µ-([Image: see text] H(8)] (1, n = 3; 2, n = 4) with an excess of KOH in a 1:1 benzene/methanol mixture at room temperature in air affords new dioxygen closo-ruthenacarborane complexes [3-(η(2)-O(2))-3,3,8-[Ph(2)P(CH(2))(n)PPh-µ-([Image: see text] H(8)]...

Descripción completa

Detalles Bibliográficos
Autores principales: Kostukovich, Alexander Y., D’yachihin, Dmitrii I., Dolgushin, Fedor M., Smol’yakov, Alexander F., Godovikov, Ivan A., Chizhevsky, Igor T.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: MDPI 2014
Materias:
Article
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6271427/
https://www.ncbi.nlm.nih.gov/pubmed/24886937
http://dx.doi.org/10.3390/molecules19067094
_version_ 1783376926328487936
author Kostukovich, Alexander Y.
D’yachihin, Dmitrii I.
Dolgushin, Fedor M.
Smol’yakov, Alexander F.
Godovikov, Ivan A.
Chizhevsky, Igor T.
author_facet Kostukovich, Alexander Y.
D’yachihin, Dmitrii I.
Dolgushin, Fedor M.
Smol’yakov, Alexander F.
Godovikov, Ivan A.
Chizhevsky, Igor T.
author_sort Kostukovich, Alexander Y.
collection PubMed
description Treatment of [3-Cl-3,3,8-[Ph(2)P(CH(2))(n)PPh-µ-([Image: see text] H(8)] (1, n = 3; 2, n = 4) with an excess of KOH in a 1:1 benzene/methanol mixture at room temperature in air affords new dioxygen closo-ruthenacarborane complexes [3-(η(2)-O(2))-3,3,8-[Ph(2)P(CH(2))(n)PPh-µ-([Image: see text] H(8)] (3, n = 3) and (4, n = 4) in 42.5% and 45.8% yield respectively. The structures of dioxygen complexes 3 and 4 were established by single-crystal X-ray diffraction. The IR and multinuclear NMR data [(1)H, (13)C{(1)H}, (31)P{(1)H} and (11)B{(1)H}] along with 2D HSQC correlation spectra for the new dioxygen closo-ruthenacarboranes are discussed.
format Online
Article
Text
id pubmed-6271427
institution National Center for Biotechnology Information
language English
publishDate 2014
publisher MDPI
record_format MEDLINE/PubMed
spelling pubmed-62714272018-12-21 An Unusual Conversion of Paramagnetic [3-Cl-3,3,8-{Ph(2)P(CH(2))(n)PPh-µ-([Image: see text] H(8)] (n = 3 and 4) to Form the First 18-Electron P-Phenylene ortho-Cycloboronated closo-Ruthenacarboranes with a Dioxygen Ligand Kostukovich, Alexander Y. D’yachihin, Dmitrii I. Dolgushin, Fedor M. Smol’yakov, Alexander F. Godovikov, Ivan A. Chizhevsky, Igor T. Molecules Article Treatment of [3-Cl-3,3,8-[Ph(2)P(CH(2))(n)PPh-µ-([Image: see text] H(8)] (1, n = 3; 2, n = 4) with an excess of KOH in a 1:1 benzene/methanol mixture at room temperature in air affords new dioxygen closo-ruthenacarborane complexes [3-(η(2)-O(2))-3,3,8-[Ph(2)P(CH(2))(n)PPh-µ-([Image: see text] H(8)] (3, n = 3) and (4, n = 4) in 42.5% and 45.8% yield respectively. The structures of dioxygen complexes 3 and 4 were established by single-crystal X-ray diffraction. The IR and multinuclear NMR data [(1)H, (13)C{(1)H}, (31)P{(1)H} and (11)B{(1)H}] along with 2D HSQC correlation spectra for the new dioxygen closo-ruthenacarboranes are discussed. MDPI 2014-05-30 /pmc/articles/PMC6271427/ /pubmed/24886937 http://dx.doi.org/10.3390/molecules19067094 Text en © 2014 by the authors. licensee MDPI, Basel, Switzerland. This article is an open access article distributed under the terms and conditions of the Creative Commons Attribution license (http://creativecommons.org/licenses/by/3.0/).
spellingShingle Article
Kostukovich, Alexander Y.
D’yachihin, Dmitrii I.
Dolgushin, Fedor M.
Smol’yakov, Alexander F.
Godovikov, Ivan A.
Chizhevsky, Igor T.
An Unusual Conversion of Paramagnetic [3-Cl-3,3,8-{Ph(2)P(CH(2))(n)PPh-µ-([Image: see text] H(8)] (n = 3 and 4) to Form the First 18-Electron P-Phenylene ortho-Cycloboronated closo-Ruthenacarboranes with a Dioxygen Ligand
title An Unusual Conversion of Paramagnetic [3-Cl-3,3,8-{Ph(2)P(CH(2))(n)PPh-µ-([Image: see text] H(8)] (n = 3 and 4) to Form the First 18-Electron P-Phenylene ortho-Cycloboronated closo-Ruthenacarboranes with a Dioxygen Ligand
title_full An Unusual Conversion of Paramagnetic [3-Cl-3,3,8-{Ph(2)P(CH(2))(n)PPh-µ-([Image: see text] H(8)] (n = 3 and 4) to Form the First 18-Electron P-Phenylene ortho-Cycloboronated closo-Ruthenacarboranes with a Dioxygen Ligand
title_fullStr An Unusual Conversion of Paramagnetic [3-Cl-3,3,8-{Ph(2)P(CH(2))(n)PPh-µ-([Image: see text] H(8)] (n = 3 and 4) to Form the First 18-Electron P-Phenylene ortho-Cycloboronated closo-Ruthenacarboranes with a Dioxygen Ligand
title_full_unstemmed An Unusual Conversion of Paramagnetic [3-Cl-3,3,8-{Ph(2)P(CH(2))(n)PPh-µ-([Image: see text] H(8)] (n = 3 and 4) to Form the First 18-Electron P-Phenylene ortho-Cycloboronated closo-Ruthenacarboranes with a Dioxygen Ligand
title_short An Unusual Conversion of Paramagnetic [3-Cl-3,3,8-{Ph(2)P(CH(2))(n)PPh-µ-([Image: see text] H(8)] (n = 3 and 4) to Form the First 18-Electron P-Phenylene ortho-Cycloboronated closo-Ruthenacarboranes with a Dioxygen Ligand
title_sort unusual conversion of paramagnetic [3-cl-3,3,8-{ph(2)p(ch(2))(n)pph-µ-([image: see text] h(8)] (n = 3 and 4) to form the first 18-electron p-phenylene ortho-cycloboronated closo-ruthenacarboranes with a dioxygen ligand
topic Article
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6271427/
https://www.ncbi.nlm.nih.gov/pubmed/24886937
http://dx.doi.org/10.3390/molecules19067094
work_keys_str_mv AT kostukovichalexandery anunusualconversionofparamagnetic3cl338ph2pch2npphμimageseetexth8n3and4toformthefirst18electronpphenyleneorthocycloboronatedclosoruthenacarboraneswithadioxygenligand
AT dyachihindmitriii anunusualconversionofparamagnetic3cl338ph2pch2npphμimageseetexth8n3and4toformthefirst18electronpphenyleneorthocycloboronatedclosoruthenacarboraneswithadioxygenligand
AT dolgushinfedorm anunusualconversionofparamagnetic3cl338ph2pch2npphμimageseetexth8n3and4toformthefirst18electronpphenyleneorthocycloboronatedclosoruthenacarboraneswithadioxygenligand
AT smolyakovalexanderf anunusualconversionofparamagnetic3cl338ph2pch2npphμimageseetexth8n3and4toformthefirst18electronpphenyleneorthocycloboronatedclosoruthenacarboraneswithadioxygenligand
AT godovikovivana anunusualconversionofparamagnetic3cl338ph2pch2npphμimageseetexth8n3and4toformthefirst18electronpphenyleneorthocycloboronatedclosoruthenacarboraneswithadioxygenligand
AT chizhevskyigort anunusualconversionofparamagnetic3cl338ph2pch2npphμimageseetexth8n3and4toformthefirst18electronpphenyleneorthocycloboronatedclosoruthenacarboraneswithadioxygenligand
AT kostukovichalexandery unusualconversionofparamagnetic3cl338ph2pch2npphμimageseetexth8n3and4toformthefirst18electronpphenyleneorthocycloboronatedclosoruthenacarboraneswithadioxygenligand
AT dyachihindmitriii unusualconversionofparamagnetic3cl338ph2pch2npphμimageseetexth8n3and4toformthefirst18electronpphenyleneorthocycloboronatedclosoruthenacarboraneswithadioxygenligand
AT dolgushinfedorm unusualconversionofparamagnetic3cl338ph2pch2npphμimageseetexth8n3and4toformthefirst18electronpphenyleneorthocycloboronatedclosoruthenacarboraneswithadioxygenligand
AT smolyakovalexanderf unusualconversionofparamagnetic3cl338ph2pch2npphμimageseetexth8n3and4toformthefirst18electronpphenyleneorthocycloboronatedclosoruthenacarboraneswithadioxygenligand
AT godovikovivana unusualconversionofparamagnetic3cl338ph2pch2npphμimageseetexth8n3and4toformthefirst18electronpphenyleneorthocycloboronatedclosoruthenacarboraneswithadioxygenligand
AT chizhevskyigort unusualconversionofparamagnetic3cl338ph2pch2npphμimageseetexth8n3and4toformthefirst18electronpphenyleneorthocycloboronatedclosoruthenacarboraneswithadioxygenligand

Ejemplares similares