An Unusual Conversion of Paramagnetic [3-Cl-3,3,8-{Ph(2)P(CH(2))(n)PPh-µ-([Image: see text] H(8)] (n = 3 and 4) to Form the First 18-Electron P-Phenylene ortho-Cycloboronated closo-Ruthenacarboranes with a Dioxygen Ligand

Treatment of [3-Cl-3,3,8-[Ph(2)P(CH(2))(n)PPh-µ-([Image: see text] H(8)] (1, n = 3; 2, n = 4) with an excess of KOH in a 1:1 benzene/methanol mixture at room temperature in air affords new dioxygen closo-ruthenacarborane complexes [3-(η(2)-O(2))-3,3,8-[Ph(2)P(CH(2))(n)PPh-µ-([Image: see text] H(8)]...

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Detalles Bibliográficos
Autores principales: Kostukovich, Alexander Y., D’yachihin, Dmitrii I., Dolgushin, Fedor M., Smol’yakov, Alexander F., Godovikov, Ivan A., Chizhevsky, Igor T.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: MDPI 2014
Materias:
Article
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6271427/
https://www.ncbi.nlm.nih.gov/pubmed/24886937
http://dx.doi.org/10.3390/molecules19067094

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