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Chiroptical Properties and the Racemization of Pyrene and Tetrathiafulvalene-Substituted Allene: Substitution and Solvent Effects on Racemization in Tetrathiafulvalenylallene

Dissymmetric 1,3-diphenylallene derivative 3 connected with 4,5-bis(methyl-thio)tetrathiafulvalenyl and 1-pyrenyl substituents was prepared and characterized. The molecular structure was determined by X-ray crystallographic analysis. Optical resolution was accomplished using a recycling chiral HPLC,...

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Detalles Bibliográficos
Autores principales:	Hasegawa, Masashi, Iwata, Seiya, Sone, Yasuto, Endo, Junta, Matsuzawa, Hideyo, Mazaki, Yasuhiro
Formato:	Online Artículo Texto
Lenguaje:	English
Publicado:	MDPI 2014
Materias:	Article
Acceso en línea:	https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6271782/ https://www.ncbi.nlm.nih.gov/pubmed/24599123 http://dx.doi.org/10.3390/molecules19032829

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