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Glycosylation of a Newly Functionalized Orthoester Derivative

Tandem glycosylation of the 6-O-Fmoc-substituted benzyl orthoester derivative 2a was carried out in moderate yields by electrogenerated acid (EGA). The Fmoc group was effectively removed under mild basic conditions, and the product was submitted to the subsequent glycosylation.

Detalles Bibliográficos
Autores principales: Kawa, Kohei, Saitoh, Tsuyoshi, Kaji, Eisuke, Nishiyama, Shigeru
Formato: Online Artículo Texto
Lenguaje:English
Publicado: MDPI 2014
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6271792/
https://www.ncbi.nlm.nih.gov/pubmed/24566324
http://dx.doi.org/10.3390/molecules19022602
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author Kawa, Kohei
Saitoh, Tsuyoshi
Kaji, Eisuke
Nishiyama, Shigeru
author_facet Kawa, Kohei
Saitoh, Tsuyoshi
Kaji, Eisuke
Nishiyama, Shigeru
author_sort Kawa, Kohei
collection PubMed
description Tandem glycosylation of the 6-O-Fmoc-substituted benzyl orthoester derivative 2a was carried out in moderate yields by electrogenerated acid (EGA). The Fmoc group was effectively removed under mild basic conditions, and the product was submitted to the subsequent glycosylation.
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spelling pubmed-62717922018-12-20 Glycosylation of a Newly Functionalized Orthoester Derivative Kawa, Kohei Saitoh, Tsuyoshi Kaji, Eisuke Nishiyama, Shigeru Molecules Article Tandem glycosylation of the 6-O-Fmoc-substituted benzyl orthoester derivative 2a was carried out in moderate yields by electrogenerated acid (EGA). The Fmoc group was effectively removed under mild basic conditions, and the product was submitted to the subsequent glycosylation. MDPI 2014-02-24 /pmc/articles/PMC6271792/ /pubmed/24566324 http://dx.doi.org/10.3390/molecules19022602 Text en © 2014 by the authors. Licensee MDPI, Basel, Switzerland. This article is an open access article distributed under the terms and conditions of the Creative Commons Attribution license (http://creativecommons.org/licenses/by/3.0/).
spellingShingle Article
Kawa, Kohei
Saitoh, Tsuyoshi
Kaji, Eisuke
Nishiyama, Shigeru
Glycosylation of a Newly Functionalized Orthoester Derivative
title Glycosylation of a Newly Functionalized Orthoester Derivative
title_full Glycosylation of a Newly Functionalized Orthoester Derivative
title_fullStr Glycosylation of a Newly Functionalized Orthoester Derivative
title_full_unstemmed Glycosylation of a Newly Functionalized Orthoester Derivative
title_short Glycosylation of a Newly Functionalized Orthoester Derivative
title_sort glycosylation of a newly functionalized orthoester derivative
topic Article
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6271792/
https://www.ncbi.nlm.nih.gov/pubmed/24566324
http://dx.doi.org/10.3390/molecules19022602
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AT nishiyamashigeru glycosylationofanewlyfunctionalizedorthoesterderivative