Bifunctionalized Allenes. Part XVI. Synthesis of 3-Phosphoryl-2,5-dihydrofurans by Coinage Metal-Catalyzed Cyclo-isomerization of Phosphorylated α-Hydroxyallenes

Phosphorylated α-hydroxyallenes 1 and 2 were smoothly converted into the corresponding 2,5-dihydrofurans 3 and 4 in an 5-endo-trig cycloisomerization reaction by using 5 mol % of coinage metal salts as catalyst. Experimental conditions such as the type of the solvent, the reaction temperature, the m...

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Detalles Bibliográficos
Autores principales: Christov, Valerij Ch., Ismailov, Ismail E., Ivanov, Ivaylo K.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: MDPI 2015
Materias:
Article
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6272136/
https://www.ncbi.nlm.nih.gov/pubmed/25905604
http://dx.doi.org/10.3390/molecules20047263

Internet

https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6272136/
https://www.ncbi.nlm.nih.gov/pubmed/25905604
http://dx.doi.org/10.3390/molecules20047263

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