Enantioselective Synthesis of cis-Decalins Using Organocatalysis and Sulfonyl Nazarov Reagents

The first organocatalytic synthesis of cis-decalins using sulfonyl Nazarov reagents is reported. The Jørgensen’s catalyst directs this highly enantioselective synthesis using different cyclohexenal derivatives.

Detalles Bibliográficos
Autores principales: Peña, Javier, Silveira-Dorta, Gastón, Moro, Rosalina F., Garrido, Narciso M., Marcos, Isidro S., Sanz, Francisca, Díez, David
Formato: Online Artículo Texto
Lenguaje:English
Publicado: MDPI 2015
Materias:
Article
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6272541/
https://www.ncbi.nlm.nih.gov/pubmed/25867826
http://dx.doi.org/10.3390/molecules20046409
Descripción
Sumario:The first organocatalytic synthesis of cis-decalins using sulfonyl Nazarov reagents is reported. The Jørgensen’s catalyst directs this highly enantioselective synthesis using different cyclohexenal derivatives.

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