Enantioselective Synthesis of cis-Decalins Using Organocatalysis and Sulfonyl Nazarov Reagents

The first organocatalytic synthesis of cis-decalins using sulfonyl Nazarov reagents is reported. The Jørgensen’s catalyst directs this highly enantioselective synthesis using different cyclohexenal derivatives.

Detalles Bibliográficos
Autores principales: Peña, Javier, Silveira-Dorta, Gastón, Moro, Rosalina F., Garrido, Narciso M., Marcos, Isidro S., Sanz, Francisca, Díez, David
Formato: Online Artículo Texto
Lenguaje:English
Publicado: MDPI 2015
Materias:
Article
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6272541/
https://www.ncbi.nlm.nih.gov/pubmed/25867826
http://dx.doi.org/10.3390/molecules20046409
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author Peña, Javier
Silveira-Dorta, Gastón
Moro, Rosalina F.
Garrido, Narciso M.
Marcos, Isidro S.
Sanz, Francisca
Díez, David
author_facet Peña, Javier
Silveira-Dorta, Gastón
Moro, Rosalina F.
Garrido, Narciso M.
Marcos, Isidro S.
Sanz, Francisca
Díez, David
author_sort Peña, Javier
collection PubMed
description The first organocatalytic synthesis of cis-decalins using sulfonyl Nazarov reagents is reported. The Jørgensen’s catalyst directs this highly enantioselective synthesis using different cyclohexenal derivatives.
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spelling pubmed-62725412018-12-03 Enantioselective Synthesis of cis-Decalins Using Organocatalysis and Sulfonyl Nazarov Reagents Peña, Javier Silveira-Dorta, Gastón Moro, Rosalina F. Garrido, Narciso M. Marcos, Isidro S. Sanz, Francisca Díez, David Molecules Article The first organocatalytic synthesis of cis-decalins using sulfonyl Nazarov reagents is reported. The Jørgensen’s catalyst directs this highly enantioselective synthesis using different cyclohexenal derivatives. MDPI 2015-04-10 /pmc/articles/PMC6272541/ /pubmed/25867826 http://dx.doi.org/10.3390/molecules20046409 Text en © 2015 by the authors. Licensee MDPI, Basel, Switzerland. This article is an open access article distributed under the terms and conditions of the Creative Commons Attribution license (http://creativecommons.org/licenses/by/4.0/).
spellingShingle Article
Peña, Javier
Silveira-Dorta, Gastón
Moro, Rosalina F.
Garrido, Narciso M.
Marcos, Isidro S.
Sanz, Francisca
Díez, David
Enantioselective Synthesis of cis-Decalins Using Organocatalysis and Sulfonyl Nazarov Reagents
title Enantioselective Synthesis of cis-Decalins Using Organocatalysis and Sulfonyl Nazarov Reagents
title_full Enantioselective Synthesis of cis-Decalins Using Organocatalysis and Sulfonyl Nazarov Reagents
title_fullStr Enantioselective Synthesis of cis-Decalins Using Organocatalysis and Sulfonyl Nazarov Reagents
title_full_unstemmed Enantioselective Synthesis of cis-Decalins Using Organocatalysis and Sulfonyl Nazarov Reagents
title_short Enantioselective Synthesis of cis-Decalins Using Organocatalysis and Sulfonyl Nazarov Reagents
title_sort enantioselective synthesis of cis-decalins using organocatalysis and sulfonyl nazarov reagents
topic Article
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6272541/
https://www.ncbi.nlm.nih.gov/pubmed/25867826
http://dx.doi.org/10.3390/molecules20046409
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