Cargando…

Enantioselective Synthesis of cis-Decalins Using Organocatalysis and Sulfonyl Nazarov Reagents

The first organocatalytic synthesis of cis-decalins using sulfonyl Nazarov reagents is reported. The Jørgensen’s catalyst directs this highly enantioselective synthesis using different cyclohexenal derivatives.

Detalles Bibliográficos
Autores principales:	Peña, Javier, Silveira-Dorta, Gastón, Moro, Rosalina F., Garrido, Narciso M., Marcos, Isidro S., Sanz, Francisca, Díez, David
Formato:	Online Artículo Texto
Lenguaje:	English
Publicado:	MDPI 2015
Materias:	Article
Acceso en línea:	https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6272541/ https://www.ncbi.nlm.nih.gov/pubmed/25867826 http://dx.doi.org/10.3390/molecules20046409

Ejemplares similares

Salen Promoted Enantioselective Nazarov Cyclizations of Activated and Unactivated Dienones
por: Hutson, Gerri E., et al.
Publicado: (2013)

Asymmetric Gold(I)‐Catalyzed Tandem Hydroarylation–Nazarov Cyclization: Enantioselective Access to Cyclopentenones
por: Solas, Marta, et al.
Publicado: (2022)

Enantioselective organocatalysis: reactions and experimental procedures
por: Dalko, Peter I
Publicado: (2007)

Crystal structure of (2R*,3aR*)-2-phenylsulfonyl-2,3,3a,4,5,6-hexahydropyrrolo[1,2-b]isoxazole
por: Hernández, Yaiza, et al.
Publicado: (2017)

Enantioselective dearomatization reactions of heteroarenes by anion-binding organocatalysis
por: Aleksiev, Martin, et al.
Publicado: (2023)

Enantioselective Nazarov cyclization of indole enones cooperatively catalyzed by Lewis acids and chiral Brønsted acids
por: Wang, Guo-Peng, et al.
Publicado: (2017)

(2R,3S,4R)-3,4-Isopropylidenedioxy-2-(phenylsulfonylmethyl)pyrrolidin-1-ol
por: Flores, Mari Fe, et al.
Publicado: (2012)

Organocatalysis in Synthesis: L-Proline as an Enantioselective Catalyst in the Synthesis of Pyrans and Thiopyrans
por: Elnagdi, Noha M. Hilmy, et al.
Publicado: (2012)

Single-Flask Enantioselective Synthesis of α-Amino Acid Esters by Organocatalysis
por: Battaglia, Vincenzo, et al.
Publicado: (2023)

cis-Decalin-containing tetramic acids as inhibitors of insect steroidogenic glutathione S-transferase Noppera-bo
por: Kato, Naoki, et al.
Publicado: (2023)

Enantioselective Cycloaddition of Münchnones onto [60]Fullerene: Organocatalysis versus Metal Catalysis
por: Marco-Martínez, Juan, et al.
Publicado: (2014)

Enantioselective Formal α‐Methylation and α‐Benzylation of Aldehydes by Means of Photo‐organocatalysis
por: Filippini, Giacomo, et al.
Publicado: (2017)

Mechanochemical Organocatalysis: Do High Enantioselectivities Contradict What We Might Expect?
por: Williams, Matthew T. J., et al.
Publicado: (2021)

Easy Access to Polyfunctionalized Chiral Decalins
por: Santalla, Hugo, et al.
Publicado: (2020)

A combined continuous microflow photochemistry and asymmetric organocatalysis approach for the enantioselective synthesis of tetrahydroquinolines
por: Sugiono, Erli, et al.
Publicado: (2013)

Combining silver- and organocatalysis: an enantioselective sequential catalytic approach towards pyrano-annulated pyrazoles
por: Hack, Daniel, et al.
Publicado: (2015)

Enantioselective Organocatalysis-Based Synthesis of 3-Hydroxy Fatty Acids and Fatty γ-Lactones
por: Bourboula, Asimina, et al.
Publicado: (2019)

Enantioselective Sulfonylation Reactions Mediated by a Tetrapeptide Catalyst
por: Fiori, Kristin Williams, et al.
Publicado: (2009)

Organocatalysis
por: List, Benjamin
Publicado: (2012)

Isolation of Pyrrolocins A–C: cis- and trans-Decalin Tetramic Acid Antibiotics from an Endophytic Fungal-Derived Pathway
por: Jadulco, Raquel C., et al.
Publicado: (2014)

Rh-Catalyzed Highly Enantioselective Synthesis of Aliphatic Sulfonyl Fluorides
por: Moku, Balakrishna, et al.
Publicado: (2019)

Palladium and Organocatalysis: An Excellent Recipe for Asymmetric Synthesis
por: Fernández-Ibañez, M. Ángeles, et al.
Publicado: (2013)

Catalytic Enantioselective Addition of Organozirconium Reagents to Aldehydes
por: Solà, Ricard, et al.
Publicado: (2018)

A general, enantioselective synthesis of N-alkyl terminal aziridines and C2-functionalized azetidines via organocatalysis
por: Senter, Timothy J., et al.
Publicado: (2015)

Tetrabutylammonium Iodide–Promoted Thiolation of Oxindoles Using Sulfonyl Chlorides as Sulfenylation Reagents
por: Zhao, Xia, et al.
Publicado: (2017)

Theoretical Perspectives in Organocatalysis
por: Melnyk, Nika, et al.
Publicado: (2022)

Organocatalysis with carbon nitrides
por: Ruban, Sujanya Maria, et al.
Publicado: (2023)

Enantioselective Oxidative Rearrangements with Chiral Hypervalent Iodine Reagents
por: Brown, Michael, et al.
Publicado: (2016)

Catalytic Enantioselective Addition of Alkylzirconium Reagents to Aliphatic Aldehydes
por: Vaccari, Jade, et al.
Publicado: (2021)

Enantioselective aerobic oxidative cross-dehydrogenative coupling of glycine derivatives with ketones and aldehydes via cooperative photoredox catalysis and organocatalysis
por: Yang, Xiaorong, et al.
Publicado: (2020)

A Nazarov‐Ene Tandem Reaction for the Stereoselective Construction of Spiro Compounds
por: Etling, Christoph, et al.
Publicado: (2021)

Molecular Basis for Two Stereoselective Diels–Alderases that Produce Decalin Skeletons
por: Fujiyama, Keisuke, et al.
Publicado: (2021)

Synthesis of a New Chiral Pyrrolidine †
por: Flores, Mari Fe., et al.
Publicado: (2010)

Cross-trienamines in Asymmetric Organocatalysis
por: Halskov, Kim Søholm, et al.
Publicado: (2012)

Chiral phosphines in nucleophilic organocatalysis
por: Xiao, Yumei, et al.
Publicado: (2014)

New advances in asymmetric organocatalysis
por: Šebesta, Radovan
Publicado: (2022)

Electrostatic Interactions in Asymmetric Organocatalysis
por: Maji, Rajat, et al.
Publicado: (2023)

Catalytic enantioselective addition of Grignard reagents to aromatic silyl ketimines
por: Rong, Jiawei, et al.
Publicado: (2016)

Enyne diketones as substrate in asymmetric Nazarov cyclization for construction of chiral allene cyclopentenones
por: Tang, Shengbiao, et al.
Publicado: (2022)

Elsinopirins A–D, Decalin Polyketides from the Ascomycete Elsinoё pyri
por: Surup, Frank, et al.
Publicado: (2018)

Cannot write session to /tmp/vufind_sessions/sess_f2re1stlfhrb1uci2ciutt3h78