Relative Stability of cis- and trans-Hydrindanones

The relative stabilities of several cis- and trans-hydrindanones were compared using both isomerization experiments and MM2 calculations. The generally believed rule that cis-hydrindanones are more stable than trans-isomers is applicable, but is not always true. This review introduces examples, main...

Descripción completa

Detalles Bibliográficos
Autor principal: Tori, Motoo
Formato: Online Artículo Texto
Lenguaje:English
Publicado: MDPI 2015
Materias:
Review
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6272565/
https://www.ncbi.nlm.nih.gov/pubmed/25599153
http://dx.doi.org/10.3390/molecules20011509
_version_ 1783377186728706048
author Tori, Motoo
author_facet Tori, Motoo
author_sort Tori, Motoo
collection PubMed
description The relative stabilities of several cis- and trans-hydrindanones were compared using both isomerization experiments and MM2 calculations. The generally believed rule that cis-hydrindanones are more stable than trans-isomers is applicable, but is not always true. This review introduces examples, mainly from studies in our laboratory, to explain these facts.
format Online
Article
Text
id pubmed-6272565
institution National Center for Biotechnology Information
language English
publishDate 2015
publisher MDPI
record_format MEDLINE/PubMed
spelling pubmed-62725652018-12-28 Relative Stability of cis- and trans-Hydrindanones Tori, Motoo Molecules Review The relative stabilities of several cis- and trans-hydrindanones were compared using both isomerization experiments and MM2 calculations. The generally believed rule that cis-hydrindanones are more stable than trans-isomers is applicable, but is not always true. This review introduces examples, mainly from studies in our laboratory, to explain these facts. MDPI 2015-01-15 /pmc/articles/PMC6272565/ /pubmed/25599153 http://dx.doi.org/10.3390/molecules20011509 Text en © 2015 by the authors. Licensee MDPI, Basel, Switzerland. This article is an open access article distributed under the terms and conditions of the Creative Commons Attribution license (http://creativecommons.org/licenses/by/4.0/).
spellingShingle Review
Tori, Motoo
Relative Stability of cis- and trans-Hydrindanones
title Relative Stability of cis- and trans-Hydrindanones
title_full Relative Stability of cis- and trans-Hydrindanones
title_fullStr Relative Stability of cis- and trans-Hydrindanones
title_full_unstemmed Relative Stability of cis- and trans-Hydrindanones
title_short Relative Stability of cis- and trans-Hydrindanones
title_sort relative stability of cis- and trans-hydrindanones
topic Review
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6272565/
https://www.ncbi.nlm.nih.gov/pubmed/25599153
http://dx.doi.org/10.3390/molecules20011509
work_keys_str_mv AT torimotoo relativestabilityofcisandtranshydrindanones

Ejemplares similares