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Seven-Membered Rings through Metal-Free Rearrangement Mediated by Hypervalent Iodine

A versatile and metal-free approach for the synthesis of carbocycles and of heterocycles bearing seven- and eight-membered rings is described. The strategy is based on ring expansion of 1-vinylcycloalkanols (or the corresponding silyl or methyl ether) mediated by the hypervalent iodine reagent HTIB...

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Detalles Bibliográficos
Autores principales:	Silva, Siguara Bastos Lemos, Torre, Adriana Della, de Carvalho, João Ernesto, Ruiz, Ana Lúcia Tasca Gois, Silva, Luiz F.
Formato:	Online Artículo Texto
Lenguaje:	English
Publicado:	MDPI 2015
Materias:	Article
Acceso en línea:	https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6272645/ https://www.ncbi.nlm.nih.gov/pubmed/25599151 http://dx.doi.org/10.3390/molecules20011475

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