Electron Transfer-Induced Coupling of Haloarenes to Styrenes and 1,1-Diphenylethenes Triggered by Diketopiperazines and Potassium tert-Butoxide

The coupling of haloarenes to styrenes and 1,1-diarylethenes has been achieved with potassium tert-butoxide in the presence of N,N'-dialkyldiketopiperazines. In contrast to previously reported reactions where phenanthroline has been used to mediate the reactions, the use of diketopiperazines ca...

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Detalles Bibliográficos
Autores principales: Doni, Eswararao, Zhou, Shengze, Murphy, John A.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: MDPI 2015
Materias:
Communication
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6272703/
https://www.ncbi.nlm.nih.gov/pubmed/25621421
http://dx.doi.org/10.3390/molecules20021755
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author Doni, Eswararao
Zhou, Shengze
Murphy, John A.
author_facet Doni, Eswararao
Zhou, Shengze
Murphy, John A.
author_sort Doni, Eswararao
collection PubMed
description The coupling of haloarenes to styrenes and 1,1-diarylethenes has been achieved with potassium tert-butoxide in the presence of N,N'-dialkyldiketopiperazines. In contrast to previously reported reactions where phenanthroline has been used to mediate the reactions, the use of diketopiperazines can lead to either 1,1,2-triarylethenes or 1,1,2-triarylethanes, depending on the conditions used.
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spelling pubmed-62727032018-12-13 Electron Transfer-Induced Coupling of Haloarenes to Styrenes and 1,1-Diphenylethenes Triggered by Diketopiperazines and Potassium tert-Butoxide Doni, Eswararao Zhou, Shengze Murphy, John A. Molecules Communication The coupling of haloarenes to styrenes and 1,1-diarylethenes has been achieved with potassium tert-butoxide in the presence of N,N'-dialkyldiketopiperazines. In contrast to previously reported reactions where phenanthroline has been used to mediate the reactions, the use of diketopiperazines can lead to either 1,1,2-triarylethenes or 1,1,2-triarylethanes, depending on the conditions used. MDPI 2015-01-22 /pmc/articles/PMC6272703/ /pubmed/25621421 http://dx.doi.org/10.3390/molecules20021755 Text en © 2015 by the authors. Licensee MDPI, Basel, Switzerland. This article is an open access article distributed under the terms and conditions of the Creative Commons Attribution license (http://creativecommons.org/licenses/by/4.0/).
spellingShingle Communication
Doni, Eswararao
Zhou, Shengze
Murphy, John A.
Electron Transfer-Induced Coupling of Haloarenes to Styrenes and 1,1-Diphenylethenes Triggered by Diketopiperazines and Potassium tert-Butoxide
title Electron Transfer-Induced Coupling of Haloarenes to Styrenes and 1,1-Diphenylethenes Triggered by Diketopiperazines and Potassium tert-Butoxide
title_full Electron Transfer-Induced Coupling of Haloarenes to Styrenes and 1,1-Diphenylethenes Triggered by Diketopiperazines and Potassium tert-Butoxide
title_fullStr Electron Transfer-Induced Coupling of Haloarenes to Styrenes and 1,1-Diphenylethenes Triggered by Diketopiperazines and Potassium tert-Butoxide
title_full_unstemmed Electron Transfer-Induced Coupling of Haloarenes to Styrenes and 1,1-Diphenylethenes Triggered by Diketopiperazines and Potassium tert-Butoxide
title_short Electron Transfer-Induced Coupling of Haloarenes to Styrenes and 1,1-Diphenylethenes Triggered by Diketopiperazines and Potassium tert-Butoxide
title_sort electron transfer-induced coupling of haloarenes to styrenes and 1,1-diphenylethenes triggered by diketopiperazines and potassium tert-butoxide
topic Communication
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6272703/
https://www.ncbi.nlm.nih.gov/pubmed/25621421
http://dx.doi.org/10.3390/molecules20021755
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AT zhoushengze electrontransferinducedcouplingofhaloarenestostyrenesand11diphenylethenestriggeredbydiketopiperazinesandpotassiumtertbutoxide
AT murphyjohna electrontransferinducedcouplingofhaloarenestostyrenesand11diphenylethenestriggeredbydiketopiperazinesandpotassiumtertbutoxide

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