Silver(I) 2,2'-(1,2-Phenylenedisulfanediyl)diacetic Acid as a Molecular Building Block for a Silver(I)-Cadmium(II) Coordination Polymer

Starting from heterotopic multidentate ligand 2,2'-(1,2-phenylenedisulfanediyl)diacetic acid, (R(S),R(S),R(S),R(S)/S(S),S(S),S(S),S(S))-[Ag{1,2-C(6)H(4)(SCH(2)COOH)(2)-κ(2)S,S'}(2)]BF(4) (1) was prepared and further used as a building block for the synthesis of heterobimetallic Ag-Cd coord...

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Detalles Bibliográficos
Autores principales: Grosu, Ioana Georgeta, Berghof, Christiane, Lönnecke, Peter, Silaghi-Dumitrescu, Luminita, Hey-Hawkins, Evamarie
Formato: Online Artículo Texto
Lenguaje:English
Publicado: MDPI 2015
Materias:
Article
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6272712/
https://www.ncbi.nlm.nih.gov/pubmed/25946559
http://dx.doi.org/10.3390/molecules20058020
Descripción
Sumario:Starting from heterotopic multidentate ligand 2,2'-(1,2-phenylenedisulfanediyl)diacetic acid, (R(S),R(S),R(S),R(S)/S(S),S(S),S(S),S(S))-[Ag{1,2-C(6)H(4)(SCH(2)COOH)(2)-κ(2)S,S'}(2)]BF(4) (1) was prepared and further used as a building block for the synthesis of heterobimetallic Ag-Cd coordination polymer [Ag(2)Cd(2){1,2-(OOCCH(2)S)(2)C(6)H(4)}(3)(H(2)O)(3) 5H(2)O](n) (2). Both complexes were characterized by X-ray structure analysis and conventional spectroscopic techniques.

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