Cargando…

Silver(I) 2,2'-(1,2-Phenylenedisulfanediyl)diacetic Acid as a Molecular Building Block for a Silver(I)-Cadmium(II) Coordination Polymer

Starting from heterotopic multidentate ligand 2,2'-(1,2-phenylenedisulfanediyl)diacetic acid, (R(S),R(S),R(S),R(S)/S(S),S(S),S(S),S(S))-[Ag{1,2-C(6)H(4)(SCH(2)COOH)(2)-κ(2)S,S'}(2)]BF(4) (1) was prepared and further used as a building block for the synthesis of heterobimetallic Ag-Cd coord...

Descripción completa

Detalles Bibliográficos
Autores principales: Grosu, Ioana Georgeta, Berghof, Christiane, Lönnecke, Peter, Silaghi-Dumitrescu, Luminita, Hey-Hawkins, Evamarie
Formato: Online Artículo Texto
Lenguaje:English
Publicado: MDPI 2015
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6272712/
https://www.ncbi.nlm.nih.gov/pubmed/25946559
http://dx.doi.org/10.3390/molecules20058020
_version_ 1783377220683694080
author Grosu, Ioana Georgeta
Berghof, Christiane
Lönnecke, Peter
Silaghi-Dumitrescu, Luminita
Hey-Hawkins, Evamarie
author_facet Grosu, Ioana Georgeta
Berghof, Christiane
Lönnecke, Peter
Silaghi-Dumitrescu, Luminita
Hey-Hawkins, Evamarie
author_sort Grosu, Ioana Georgeta
collection PubMed
description Starting from heterotopic multidentate ligand 2,2'-(1,2-phenylenedisulfanediyl)diacetic acid, (R(S),R(S),R(S),R(S)/S(S),S(S),S(S),S(S))-[Ag{1,2-C(6)H(4)(SCH(2)COOH)(2)-κ(2)S,S'}(2)]BF(4) (1) was prepared and further used as a building block for the synthesis of heterobimetallic Ag-Cd coordination polymer [Ag(2)Cd(2){1,2-(OOCCH(2)S)(2)C(6)H(4)}(3)(H(2)O)(3) 5H(2)O](n) (2). Both complexes were characterized by X-ray structure analysis and conventional spectroscopic techniques.
format Online
Article
Text
id pubmed-6272712
institution National Center for Biotechnology Information
language English
publishDate 2015
publisher MDPI
record_format MEDLINE/PubMed
spelling pubmed-62727122019-01-07 Silver(I) 2,2'-(1,2-Phenylenedisulfanediyl)diacetic Acid as a Molecular Building Block for a Silver(I)-Cadmium(II) Coordination Polymer Grosu, Ioana Georgeta Berghof, Christiane Lönnecke, Peter Silaghi-Dumitrescu, Luminita Hey-Hawkins, Evamarie Molecules Article Starting from heterotopic multidentate ligand 2,2'-(1,2-phenylenedisulfanediyl)diacetic acid, (R(S),R(S),R(S),R(S)/S(S),S(S),S(S),S(S))-[Ag{1,2-C(6)H(4)(SCH(2)COOH)(2)-κ(2)S,S'}(2)]BF(4) (1) was prepared and further used as a building block for the synthesis of heterobimetallic Ag-Cd coordination polymer [Ag(2)Cd(2){1,2-(OOCCH(2)S)(2)C(6)H(4)}(3)(H(2)O)(3) 5H(2)O](n) (2). Both complexes were characterized by X-ray structure analysis and conventional spectroscopic techniques. MDPI 2015-05-04 /pmc/articles/PMC6272712/ /pubmed/25946559 http://dx.doi.org/10.3390/molecules20058020 Text en © 2015 by the authors. Licensee MDPI, Basel, Switzerland. This article is an open access article distributed under the terms and conditions of the Creative Commons Attribution license (http://creativecommons.org/licenses/by/4.0/).
spellingShingle Article
Grosu, Ioana Georgeta
Berghof, Christiane
Lönnecke, Peter
Silaghi-Dumitrescu, Luminita
Hey-Hawkins, Evamarie
Silver(I) 2,2'-(1,2-Phenylenedisulfanediyl)diacetic Acid as a Molecular Building Block for a Silver(I)-Cadmium(II) Coordination Polymer
title Silver(I) 2,2'-(1,2-Phenylenedisulfanediyl)diacetic Acid as a Molecular Building Block for a Silver(I)-Cadmium(II) Coordination Polymer
title_full Silver(I) 2,2'-(1,2-Phenylenedisulfanediyl)diacetic Acid as a Molecular Building Block for a Silver(I)-Cadmium(II) Coordination Polymer
title_fullStr Silver(I) 2,2'-(1,2-Phenylenedisulfanediyl)diacetic Acid as a Molecular Building Block for a Silver(I)-Cadmium(II) Coordination Polymer
title_full_unstemmed Silver(I) 2,2'-(1,2-Phenylenedisulfanediyl)diacetic Acid as a Molecular Building Block for a Silver(I)-Cadmium(II) Coordination Polymer
title_short Silver(I) 2,2'-(1,2-Phenylenedisulfanediyl)diacetic Acid as a Molecular Building Block for a Silver(I)-Cadmium(II) Coordination Polymer
title_sort silver(i) 2,2'-(1,2-phenylenedisulfanediyl)diacetic acid as a molecular building block for a silver(i)-cadmium(ii) coordination polymer
topic Article
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6272712/
https://www.ncbi.nlm.nih.gov/pubmed/25946559
http://dx.doi.org/10.3390/molecules20058020
work_keys_str_mv AT grosuioanageorgeta silveri2212phenylenedisulfanediyldiaceticacidasamolecularbuildingblockforasilvericadmiumiicoordinationpolymer
AT berghofchristiane silveri2212phenylenedisulfanediyldiaceticacidasamolecularbuildingblockforasilvericadmiumiicoordinationpolymer
AT lonneckepeter silveri2212phenylenedisulfanediyldiaceticacidasamolecularbuildingblockforasilvericadmiumiicoordinationpolymer
AT silaghidumitresculuminita silveri2212phenylenedisulfanediyldiaceticacidasamolecularbuildingblockforasilvericadmiumiicoordinationpolymer
AT heyhawkinsevamarie silveri2212phenylenedisulfanediyldiaceticacidasamolecularbuildingblockforasilvericadmiumiicoordinationpolymer