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Silver(I) 2,2'-(1,2-Phenylenedisulfanediyl)diacetic Acid as a Molecular Building Block for a Silver(I)-Cadmium(II) Coordination Polymer
Starting from heterotopic multidentate ligand 2,2'-(1,2-phenylenedisulfanediyl)diacetic acid, (R(S),R(S),R(S),R(S)/S(S),S(S),S(S),S(S))-[Ag{1,2-C(6)H(4)(SCH(2)COOH)(2)-κ(2)S,S'}(2)]BF(4) (1) was prepared and further used as a building block for the synthesis of heterobimetallic Ag-Cd coord...
Autores principales: | , , , , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
MDPI
2015
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6272712/ https://www.ncbi.nlm.nih.gov/pubmed/25946559 http://dx.doi.org/10.3390/molecules20058020 |
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author | Grosu, Ioana Georgeta Berghof, Christiane Lönnecke, Peter Silaghi-Dumitrescu, Luminita Hey-Hawkins, Evamarie |
author_facet | Grosu, Ioana Georgeta Berghof, Christiane Lönnecke, Peter Silaghi-Dumitrescu, Luminita Hey-Hawkins, Evamarie |
author_sort | Grosu, Ioana Georgeta |
collection | PubMed |
description | Starting from heterotopic multidentate ligand 2,2'-(1,2-phenylenedisulfanediyl)diacetic acid, (R(S),R(S),R(S),R(S)/S(S),S(S),S(S),S(S))-[Ag{1,2-C(6)H(4)(SCH(2)COOH)(2)-κ(2)S,S'}(2)]BF(4) (1) was prepared and further used as a building block for the synthesis of heterobimetallic Ag-Cd coordination polymer [Ag(2)Cd(2){1,2-(OOCCH(2)S)(2)C(6)H(4)}(3)(H(2)O)(3) 5H(2)O](n) (2). Both complexes were characterized by X-ray structure analysis and conventional spectroscopic techniques. |
format | Online Article Text |
id | pubmed-6272712 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2015 |
publisher | MDPI |
record_format | MEDLINE/PubMed |
spelling | pubmed-62727122019-01-07 Silver(I) 2,2'-(1,2-Phenylenedisulfanediyl)diacetic Acid as a Molecular Building Block for a Silver(I)-Cadmium(II) Coordination Polymer Grosu, Ioana Georgeta Berghof, Christiane Lönnecke, Peter Silaghi-Dumitrescu, Luminita Hey-Hawkins, Evamarie Molecules Article Starting from heterotopic multidentate ligand 2,2'-(1,2-phenylenedisulfanediyl)diacetic acid, (R(S),R(S),R(S),R(S)/S(S),S(S),S(S),S(S))-[Ag{1,2-C(6)H(4)(SCH(2)COOH)(2)-κ(2)S,S'}(2)]BF(4) (1) was prepared and further used as a building block for the synthesis of heterobimetallic Ag-Cd coordination polymer [Ag(2)Cd(2){1,2-(OOCCH(2)S)(2)C(6)H(4)}(3)(H(2)O)(3) 5H(2)O](n) (2). Both complexes were characterized by X-ray structure analysis and conventional spectroscopic techniques. MDPI 2015-05-04 /pmc/articles/PMC6272712/ /pubmed/25946559 http://dx.doi.org/10.3390/molecules20058020 Text en © 2015 by the authors. Licensee MDPI, Basel, Switzerland. This article is an open access article distributed under the terms and conditions of the Creative Commons Attribution license (http://creativecommons.org/licenses/by/4.0/). |
spellingShingle | Article Grosu, Ioana Georgeta Berghof, Christiane Lönnecke, Peter Silaghi-Dumitrescu, Luminita Hey-Hawkins, Evamarie Silver(I) 2,2'-(1,2-Phenylenedisulfanediyl)diacetic Acid as a Molecular Building Block for a Silver(I)-Cadmium(II) Coordination Polymer |
title | Silver(I) 2,2'-(1,2-Phenylenedisulfanediyl)diacetic Acid as a Molecular Building Block for a Silver(I)-Cadmium(II) Coordination Polymer |
title_full | Silver(I) 2,2'-(1,2-Phenylenedisulfanediyl)diacetic Acid as a Molecular Building Block for a Silver(I)-Cadmium(II) Coordination Polymer |
title_fullStr | Silver(I) 2,2'-(1,2-Phenylenedisulfanediyl)diacetic Acid as a Molecular Building Block for a Silver(I)-Cadmium(II) Coordination Polymer |
title_full_unstemmed | Silver(I) 2,2'-(1,2-Phenylenedisulfanediyl)diacetic Acid as a Molecular Building Block for a Silver(I)-Cadmium(II) Coordination Polymer |
title_short | Silver(I) 2,2'-(1,2-Phenylenedisulfanediyl)diacetic Acid as a Molecular Building Block for a Silver(I)-Cadmium(II) Coordination Polymer |
title_sort | silver(i) 2,2'-(1,2-phenylenedisulfanediyl)diacetic acid as a molecular building block for a silver(i)-cadmium(ii) coordination polymer |
topic | Article |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6272712/ https://www.ncbi.nlm.nih.gov/pubmed/25946559 http://dx.doi.org/10.3390/molecules20058020 |
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