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Coordination and Crystallization Molecules: Their Interactions Affecting the Dimensionality of Metalloporphyrinic SCFs
Synthetic metalloporphyrin complexes are often used as analogues of natural systems, and they can be used for the preparation of new Solid Coordination Frameworks (SCFs). In this work, a series of six metalloporphyrinic compounds constructed from different meso substituted metalloporphyrins (phenyl,...
Autores principales: | , , , , , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
MDPI
2015
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6272730/ https://www.ncbi.nlm.nih.gov/pubmed/25884550 http://dx.doi.org/10.3390/molecules20046683 |
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author | Fidalgo-Marijuan, Arkaitz Amayuelas, Eder Barandika, Gotzone Bazán, Begoña Urtiaga, Miren Karmele Arriortua, María Isabel |
author_facet | Fidalgo-Marijuan, Arkaitz Amayuelas, Eder Barandika, Gotzone Bazán, Begoña Urtiaga, Miren Karmele Arriortua, María Isabel |
author_sort | Fidalgo-Marijuan, Arkaitz |
collection | PubMed |
description | Synthetic metalloporphyrin complexes are often used as analogues of natural systems, and they can be used for the preparation of new Solid Coordination Frameworks (SCFs). In this work, a series of six metalloporphyrinic compounds constructed from different meso substituted metalloporphyrins (phenyl, carboxyphenyl and sulfonatophenyl) have been structurally characterized by means of single crystal X-ray diffraction, IR spectroscopy and elemental analysis. The compounds were classified considering the dimensionality of the crystal array, referred just to coordination bonds, into 0D, 1D and 2D compounds. This way, the structural features and relationships of those crystal structures were analyzed, in order to extract conclusions not only about the dimensionality of the networks but also about possible applications of the as-obtained compounds, focusing the interest on the interactions of coordination and crystallization molecules. These interactions provide the coordination bonds and the cohesion forces which produce SCFs with different dimensionalities. |
format | Online Article Text |
id | pubmed-6272730 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2015 |
publisher | MDPI |
record_format | MEDLINE/PubMed |
spelling | pubmed-62727302018-12-03 Coordination and Crystallization Molecules: Their Interactions Affecting the Dimensionality of Metalloporphyrinic SCFs Fidalgo-Marijuan, Arkaitz Amayuelas, Eder Barandika, Gotzone Bazán, Begoña Urtiaga, Miren Karmele Arriortua, María Isabel Molecules Article Synthetic metalloporphyrin complexes are often used as analogues of natural systems, and they can be used for the preparation of new Solid Coordination Frameworks (SCFs). In this work, a series of six metalloporphyrinic compounds constructed from different meso substituted metalloporphyrins (phenyl, carboxyphenyl and sulfonatophenyl) have been structurally characterized by means of single crystal X-ray diffraction, IR spectroscopy and elemental analysis. The compounds were classified considering the dimensionality of the crystal array, referred just to coordination bonds, into 0D, 1D and 2D compounds. This way, the structural features and relationships of those crystal structures were analyzed, in order to extract conclusions not only about the dimensionality of the networks but also about possible applications of the as-obtained compounds, focusing the interest on the interactions of coordination and crystallization molecules. These interactions provide the coordination bonds and the cohesion forces which produce SCFs with different dimensionalities. MDPI 2015-04-15 /pmc/articles/PMC6272730/ /pubmed/25884550 http://dx.doi.org/10.3390/molecules20046683 Text en © 2015 by the authors. Licensee MDPI, Basel, Switzerland. This article is an open access article distributed under the terms and conditions of the Creative Commons Attribution license (http://creativecommons.org/licenses/by/4.0/). |
spellingShingle | Article Fidalgo-Marijuan, Arkaitz Amayuelas, Eder Barandika, Gotzone Bazán, Begoña Urtiaga, Miren Karmele Arriortua, María Isabel Coordination and Crystallization Molecules: Their Interactions Affecting the Dimensionality of Metalloporphyrinic SCFs |
title | Coordination and Crystallization Molecules: Their Interactions Affecting the Dimensionality of Metalloporphyrinic SCFs |
title_full | Coordination and Crystallization Molecules: Their Interactions Affecting the Dimensionality of Metalloporphyrinic SCFs |
title_fullStr | Coordination and Crystallization Molecules: Their Interactions Affecting the Dimensionality of Metalloporphyrinic SCFs |
title_full_unstemmed | Coordination and Crystallization Molecules: Their Interactions Affecting the Dimensionality of Metalloporphyrinic SCFs |
title_short | Coordination and Crystallization Molecules: Their Interactions Affecting the Dimensionality of Metalloporphyrinic SCFs |
title_sort | coordination and crystallization molecules: their interactions affecting the dimensionality of metalloporphyrinic scfs |
topic | Article |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6272730/ https://www.ncbi.nlm.nih.gov/pubmed/25884550 http://dx.doi.org/10.3390/molecules20046683 |
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