Selenium-Mediated Synthesis of Tetrasubstituted Naphthalenes through Rearrangement

New β-keto ester substituted stilbene derivatives have been synthesized and cyclized with selenium electrophiles in the presence of Lewis acids. This now allows access to 1,2,3,4-tetrasubstituted naphthalene derivatives as cyclization and rearrangement products.

Detalles Bibliográficos
Autores principales: Tancock, James, Wirth, Thomas
Formato: Online Artículo Texto
Lenguaje:English
Publicado: MDPI 2015
Materias:
Communication
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6272767/
https://www.ncbi.nlm.nih.gov/pubmed/26076108
http://dx.doi.org/10.3390/molecules200610866
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author Tancock, James
Wirth, Thomas
author_facet Tancock, James
Wirth, Thomas
author_sort Tancock, James
collection PubMed
description New β-keto ester substituted stilbene derivatives have been synthesized and cyclized with selenium electrophiles in the presence of Lewis acids. This now allows access to 1,2,3,4-tetrasubstituted naphthalene derivatives as cyclization and rearrangement products.
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spelling pubmed-62727672018-12-31 Selenium-Mediated Synthesis of Tetrasubstituted Naphthalenes through Rearrangement Tancock, James Wirth, Thomas Molecules Communication New β-keto ester substituted stilbene derivatives have been synthesized and cyclized with selenium electrophiles in the presence of Lewis acids. This now allows access to 1,2,3,4-tetrasubstituted naphthalene derivatives as cyclization and rearrangement products. MDPI 2015-06-12 /pmc/articles/PMC6272767/ /pubmed/26076108 http://dx.doi.org/10.3390/molecules200610866 Text en © 2015 by the authors. Licensee MDPI, Basel, Switzerland. This article is an open access article distributed under the terms and conditions of the Creative Commons Attribution license (http://creativecommons.org/licenses/by/4.0/).
spellingShingle Communication
Tancock, James
Wirth, Thomas
Selenium-Mediated Synthesis of Tetrasubstituted Naphthalenes through Rearrangement
title Selenium-Mediated Synthesis of Tetrasubstituted Naphthalenes through Rearrangement
title_full Selenium-Mediated Synthesis of Tetrasubstituted Naphthalenes through Rearrangement
title_fullStr Selenium-Mediated Synthesis of Tetrasubstituted Naphthalenes through Rearrangement
title_full_unstemmed Selenium-Mediated Synthesis of Tetrasubstituted Naphthalenes through Rearrangement
title_short Selenium-Mediated Synthesis of Tetrasubstituted Naphthalenes through Rearrangement
title_sort selenium-mediated synthesis of tetrasubstituted naphthalenes through rearrangement
topic Communication
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6272767/
https://www.ncbi.nlm.nih.gov/pubmed/26076108
http://dx.doi.org/10.3390/molecules200610866
work_keys_str_mv AT tancockjames seleniummediatedsynthesisoftetrasubstitutednaphthalenesthroughrearrangement
AT wirththomas seleniummediatedsynthesisoftetrasubstitutednaphthalenesthroughrearrangement

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