Diphenylcarbene Protected by Four ortho-Iodine Groups: An Unusually Persistent Triplet Carbene

Diphenyldiazomethane with four iodine groups at the ortho positions and two tert-butyl groups at the para positions, i.e., bis(4-tert-butyl-2,6-diiodophenyl)diazomethane (1a-N(2)), was synthesized as a sterically hindered triplet carbene precursor. Irradiation of 1a-N(2) in solution effectively gene...

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Detalles Bibliográficos
Autores principales: Hirai, Katsuyuki, Bessho, Kana, Tsujita, Kosaku, Kitagawa, Toshikazu
Formato: Online Artículo Texto
Lenguaje:English
Publicado: MDPI 2016
Materias:
Article
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6272868/
https://www.ncbi.nlm.nih.gov/pubmed/27854298
http://dx.doi.org/10.3390/molecules21111545

Internet

https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6272868/
https://www.ncbi.nlm.nih.gov/pubmed/27854298
http://dx.doi.org/10.3390/molecules21111545

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