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Diphenylcarbene Protected by Four ortho-Iodine Groups: An Unusually Persistent Triplet Carbene
Diphenyldiazomethane with four iodine groups at the ortho positions and two tert-butyl groups at the para positions, i.e., bis(4-tert-butyl-2,6-diiodophenyl)diazomethane (1a-N(2)), was synthesized as a sterically hindered triplet carbene precursor. Irradiation of 1a-N(2) in solution effectively gene...
| Autores principales: | , , , |
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| Formato: | Online Artículo Texto |
| Lenguaje: | English |
| Publicado: |
MDPI
2016
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| Materias: | |
| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6272868/ https://www.ncbi.nlm.nih.gov/pubmed/27854298 http://dx.doi.org/10.3390/molecules21111545 |