Synthesis of the Fatty Esters of Solketal and Glycerol-Formal: Biobased Specialty Chemicals

The caprylic, lauric, palmitic and stearic esters of solketal and glycerol formal were synthesized with high selectivity and in good yields by a solvent-free acid catalyzed procedure. No acetal hydrolysis was observed, notwithstanding the acidic reaction conditions.

Detalles Bibliográficos
Autores principales: Perosa, Alvise, Moraschini, Andrea, Selva, Maurizio, Noè, Marco
Formato: Online Artículo Texto
Lenguaje:English
Publicado: MDPI 2016
Materias:
Article
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6273257/
https://www.ncbi.nlm.nih.gov/pubmed/26840287
http://dx.doi.org/10.3390/molecules21020170
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author Perosa, Alvise
Moraschini, Andrea
Selva, Maurizio
Noè, Marco
author_facet Perosa, Alvise
Moraschini, Andrea
Selva, Maurizio
Noè, Marco
author_sort Perosa, Alvise
collection PubMed
description The caprylic, lauric, palmitic and stearic esters of solketal and glycerol formal were synthesized with high selectivity and in good yields by a solvent-free acid catalyzed procedure. No acetal hydrolysis was observed, notwithstanding the acidic reaction conditions.
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spelling pubmed-62732572018-12-28 Synthesis of the Fatty Esters of Solketal and Glycerol-Formal: Biobased Specialty Chemicals Perosa, Alvise Moraschini, Andrea Selva, Maurizio Noè, Marco Molecules Article The caprylic, lauric, palmitic and stearic esters of solketal and glycerol formal were synthesized with high selectivity and in good yields by a solvent-free acid catalyzed procedure. No acetal hydrolysis was observed, notwithstanding the acidic reaction conditions. MDPI 2016-01-30 /pmc/articles/PMC6273257/ /pubmed/26840287 http://dx.doi.org/10.3390/molecules21020170 Text en © 2016 by the authors. Licensee MDPI, Basel, Switzerland. This article is an open access article distributed under the terms and conditions of the Creative Commons by Attribution (CC-BY) license (http://creativecommons.org/licenses/by/4.0/).
spellingShingle Article
Perosa, Alvise
Moraschini, Andrea
Selva, Maurizio
Noè, Marco
Synthesis of the Fatty Esters of Solketal and Glycerol-Formal: Biobased Specialty Chemicals
title Synthesis of the Fatty Esters of Solketal and Glycerol-Formal: Biobased Specialty Chemicals
title_full Synthesis of the Fatty Esters of Solketal and Glycerol-Formal: Biobased Specialty Chemicals
title_fullStr Synthesis of the Fatty Esters of Solketal and Glycerol-Formal: Biobased Specialty Chemicals
title_full_unstemmed Synthesis of the Fatty Esters of Solketal and Glycerol-Formal: Biobased Specialty Chemicals
title_short Synthesis of the Fatty Esters of Solketal and Glycerol-Formal: Biobased Specialty Chemicals
title_sort synthesis of the fatty esters of solketal and glycerol-formal: biobased specialty chemicals
topic Article
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6273257/
https://www.ncbi.nlm.nih.gov/pubmed/26840287
http://dx.doi.org/10.3390/molecules21020170
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AT moraschiniandrea synthesisofthefattyestersofsolketalandglycerolformalbiobasedspecialtychemicals
AT selvamaurizio synthesisofthefattyestersofsolketalandglycerolformalbiobasedspecialtychemicals
AT noemarco synthesisofthefattyestersofsolketalandglycerolformalbiobasedspecialtychemicals

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