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The Suppression of Columnar π-Stacking in 3-Adamantyl-1-phenyl-1,4-dihydrobenzo[e][1,2,4]triazin-4-yl
3-Adamantyl-1-phenyl-1,4-dihydrobenzo[e][1,2,4]triazin-4-yl (4) crystallizes as chains of radicals where the spin bearing benzotriazinyl moieties are isolated from each other. Magnetic susceptibility studies in the 5–300 K temperature region indicate that radical 4 demonstrates typical paramagnetic...
Autores principales: | , , , , , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
MDPI
2016
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6273272/ https://www.ncbi.nlm.nih.gov/pubmed/27187349 http://dx.doi.org/10.3390/molecules21050636 |
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author | Constantinides, Christos P. Berezin, Andrey A. Zissimou, Georgia A. Manoli, Maria Leitus, Gregory M. Koutentis, Panayiotis A. |
author_facet | Constantinides, Christos P. Berezin, Andrey A. Zissimou, Georgia A. Manoli, Maria Leitus, Gregory M. Koutentis, Panayiotis A. |
author_sort | Constantinides, Christos P. |
collection | PubMed |
description | 3-Adamantyl-1-phenyl-1,4-dihydrobenzo[e][1,2,4]triazin-4-yl (4) crystallizes as chains of radicals where the spin bearing benzotriazinyl moieties are isolated from each other. Magnetic susceptibility studies in the 5–300 K temperature region indicate that radical 4 demonstrates typical paramagnetic behavior stemming from non-interacting S = ½ spins. |
format | Online Article Text |
id | pubmed-6273272 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2016 |
publisher | MDPI |
record_format | MEDLINE/PubMed |
spelling | pubmed-62732722018-12-28 The Suppression of Columnar π-Stacking in 3-Adamantyl-1-phenyl-1,4-dihydrobenzo[e][1,2,4]triazin-4-yl Constantinides, Christos P. Berezin, Andrey A. Zissimou, Georgia A. Manoli, Maria Leitus, Gregory M. Koutentis, Panayiotis A. Molecules Article 3-Adamantyl-1-phenyl-1,4-dihydrobenzo[e][1,2,4]triazin-4-yl (4) crystallizes as chains of radicals where the spin bearing benzotriazinyl moieties are isolated from each other. Magnetic susceptibility studies in the 5–300 K temperature region indicate that radical 4 demonstrates typical paramagnetic behavior stemming from non-interacting S = ½ spins. MDPI 2016-05-14 /pmc/articles/PMC6273272/ /pubmed/27187349 http://dx.doi.org/10.3390/molecules21050636 Text en © 2016 by the authors. Licensee MDPI, Basel, Switzerland. This article is an open access article distributed under the terms and conditions of the Creative Commons Attribution (CC-BY) license (http://creativecommons.org/licenses/by/4.0/). |
spellingShingle | Article Constantinides, Christos P. Berezin, Andrey A. Zissimou, Georgia A. Manoli, Maria Leitus, Gregory M. Koutentis, Panayiotis A. The Suppression of Columnar π-Stacking in 3-Adamantyl-1-phenyl-1,4-dihydrobenzo[e][1,2,4]triazin-4-yl |
title | The Suppression of Columnar π-Stacking in 3-Adamantyl-1-phenyl-1,4-dihydrobenzo[e][1,2,4]triazin-4-yl |
title_full | The Suppression of Columnar π-Stacking in 3-Adamantyl-1-phenyl-1,4-dihydrobenzo[e][1,2,4]triazin-4-yl |
title_fullStr | The Suppression of Columnar π-Stacking in 3-Adamantyl-1-phenyl-1,4-dihydrobenzo[e][1,2,4]triazin-4-yl |
title_full_unstemmed | The Suppression of Columnar π-Stacking in 3-Adamantyl-1-phenyl-1,4-dihydrobenzo[e][1,2,4]triazin-4-yl |
title_short | The Suppression of Columnar π-Stacking in 3-Adamantyl-1-phenyl-1,4-dihydrobenzo[e][1,2,4]triazin-4-yl |
title_sort | suppression of columnar π-stacking in 3-adamantyl-1-phenyl-1,4-dihydrobenzo[e][1,2,4]triazin-4-yl |
topic | Article |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6273272/ https://www.ncbi.nlm.nih.gov/pubmed/27187349 http://dx.doi.org/10.3390/molecules21050636 |
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