Water and Aqueous Mixtures as Convenient Alternative Media for Organoselenium Chemistry

Even if water is the natural environment for bioorganic reactions, its use in organic chemistry is often severely limited by the high insolubility of the organic derivatives. In this review, we introduce some examples of the use of water to perform organoselenium chemistry. We mainly discuss the adv...

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Detalles Bibliográficos
Autores principales: Santi, Claudio, Jacob, Raquel G., Monti, Bonifacio, Bagnoli, Luana, Sancineto, Luca, Lenardão, Eder J.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: MDPI 2016
Materias:
Review
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6273363/
https://www.ncbi.nlm.nih.gov/pubmed/27827970
http://dx.doi.org/10.3390/molecules21111482
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author Santi, Claudio
Jacob, Raquel G.
Monti, Bonifacio
Bagnoli, Luana
Sancineto, Luca
Lenardão, Eder J.
author_facet Santi, Claudio
Jacob, Raquel G.
Monti, Bonifacio
Bagnoli, Luana
Sancineto, Luca
Lenardão, Eder J.
author_sort Santi, Claudio
collection PubMed
description Even if water is the natural environment for bioorganic reactions, its use in organic chemistry is often severely limited by the high insolubility of the organic derivatives. In this review, we introduce some examples of the use of water to perform organoselenium chemistry. We mainly discuss the advantages of this medium when the recyclability is demonstrated and when the water can control the selectivity of a reaction or enhance the reaction rate.
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spelling pubmed-62733632018-12-28 Water and Aqueous Mixtures as Convenient Alternative Media for Organoselenium Chemistry Santi, Claudio Jacob, Raquel G. Monti, Bonifacio Bagnoli, Luana Sancineto, Luca Lenardão, Eder J. Molecules Review Even if water is the natural environment for bioorganic reactions, its use in organic chemistry is often severely limited by the high insolubility of the organic derivatives. In this review, we introduce some examples of the use of water to perform organoselenium chemistry. We mainly discuss the advantages of this medium when the recyclability is demonstrated and when the water can control the selectivity of a reaction or enhance the reaction rate. MDPI 2016-11-06 /pmc/articles/PMC6273363/ /pubmed/27827970 http://dx.doi.org/10.3390/molecules21111482 Text en © 2016 by the authors. Licensee MDPI, Basel, Switzerland. This article is an open access article distributed under the terms and conditions of the Creative Commons Attribution (CC-BY) license (http://creativecommons.org/licenses/by/4.0/).
spellingShingle Review
Santi, Claudio
Jacob, Raquel G.
Monti, Bonifacio
Bagnoli, Luana
Sancineto, Luca
Lenardão, Eder J.
Water and Aqueous Mixtures as Convenient Alternative Media for Organoselenium Chemistry
title Water and Aqueous Mixtures as Convenient Alternative Media for Organoselenium Chemistry
title_full Water and Aqueous Mixtures as Convenient Alternative Media for Organoselenium Chemistry
title_fullStr Water and Aqueous Mixtures as Convenient Alternative Media for Organoselenium Chemistry
title_full_unstemmed Water and Aqueous Mixtures as Convenient Alternative Media for Organoselenium Chemistry
title_short Water and Aqueous Mixtures as Convenient Alternative Media for Organoselenium Chemistry
title_sort water and aqueous mixtures as convenient alternative media for organoselenium chemistry
topic Review
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6273363/
https://www.ncbi.nlm.nih.gov/pubmed/27827970
http://dx.doi.org/10.3390/molecules21111482
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