Preparation of Cu@Cu(2)O Nanocatalysts by Reduction of HKUST-1 for Oxidation Reaction of Catechol

HKUST-1, a copper-based metal organic framework (MOF), has been investigated as a catalyst in various reactions. However, the HKUST-1 shows low catalytic activity in the oxidation of catechol. Therefore, we synthesized Fe(3)O(4)@HKUST-1 by layer-by layer assembly strategy and Cu@Cu(2)O by reduction...

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Detalles Bibliográficos
Autores principales: Jang, Seongwan, Yoon, Chohye, Lee, Jae Myung, Park, Sungkyun, Park, Kang Hyun
Formato: Online Artículo Texto
Lenguaje:English
Publicado: MDPI 2016
Materias:
Communication
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6273573/
https://www.ncbi.nlm.nih.gov/pubmed/27827865
http://dx.doi.org/10.3390/molecules21111467
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author Jang, Seongwan
Yoon, Chohye
Lee, Jae Myung
Park, Sungkyun
Park, Kang Hyun
author_facet Jang, Seongwan
Yoon, Chohye
Lee, Jae Myung
Park, Sungkyun
Park, Kang Hyun
author_sort Jang, Seongwan
collection PubMed
description HKUST-1, a copper-based metal organic framework (MOF), has been investigated as a catalyst in various reactions. However, the HKUST-1 shows low catalytic activity in the oxidation of catechol. Therefore, we synthesized Fe(3)O(4)@HKUST-1 by layer-by layer assembly strategy and Cu@Cu(2)O by reduction of HKUST-1 for enhancement of catalytic activity. Cu@Cu(2)O nanoparticles exhibited highly effective catalytic activity in oxidation of 3,5-di-tert-butylcatechol. Through this method, MOF can maintain the original core-shell structure and be used in various other reactions with enhanced catalytic activity.
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spelling pubmed-62735732018-12-28 Preparation of Cu@Cu(2)O Nanocatalysts by Reduction of HKUST-1 for Oxidation Reaction of Catechol Jang, Seongwan Yoon, Chohye Lee, Jae Myung Park, Sungkyun Park, Kang Hyun Molecules Communication HKUST-1, a copper-based metal organic framework (MOF), has been investigated as a catalyst in various reactions. However, the HKUST-1 shows low catalytic activity in the oxidation of catechol. Therefore, we synthesized Fe(3)O(4)@HKUST-1 by layer-by layer assembly strategy and Cu@Cu(2)O by reduction of HKUST-1 for enhancement of catalytic activity. Cu@Cu(2)O nanoparticles exhibited highly effective catalytic activity in oxidation of 3,5-di-tert-butylcatechol. Through this method, MOF can maintain the original core-shell structure and be used in various other reactions with enhanced catalytic activity. MDPI 2016-11-02 /pmc/articles/PMC6273573/ /pubmed/27827865 http://dx.doi.org/10.3390/molecules21111467 Text en © 2016 by the authors. Licensee MDPI, Basel, Switzerland. This article is an open access article distributed under the terms and conditions of the Creative Commons Attribution (CC-BY) license (http://creativecommons.org/licenses/by/4.0/).
spellingShingle Communication
Jang, Seongwan
Yoon, Chohye
Lee, Jae Myung
Park, Sungkyun
Park, Kang Hyun
Preparation of Cu@Cu(2)O Nanocatalysts by Reduction of HKUST-1 for Oxidation Reaction of Catechol
title Preparation of Cu@Cu(2)O Nanocatalysts by Reduction of HKUST-1 for Oxidation Reaction of Catechol
title_full Preparation of Cu@Cu(2)O Nanocatalysts by Reduction of HKUST-1 for Oxidation Reaction of Catechol
title_fullStr Preparation of Cu@Cu(2)O Nanocatalysts by Reduction of HKUST-1 for Oxidation Reaction of Catechol
title_full_unstemmed Preparation of Cu@Cu(2)O Nanocatalysts by Reduction of HKUST-1 for Oxidation Reaction of Catechol
title_short Preparation of Cu@Cu(2)O Nanocatalysts by Reduction of HKUST-1 for Oxidation Reaction of Catechol
title_sort preparation of cu@cu(2)o nanocatalysts by reduction of hkust-1 for oxidation reaction of catechol
topic Communication
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6273573/
https://www.ncbi.nlm.nih.gov/pubmed/27827865
http://dx.doi.org/10.3390/molecules21111467
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