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High-Pressure Design of Advanced BN-Based Materials

The aim of the present review is to highlight the state of the art in high-pressure design of new advanced materials based on boron nitride. Recent experimental achievements on the governing phase transformation, nanostructuring and chemical synthesis in the systems containing boron nitride at high...

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Detalles Bibliográficos
Autores principales: Kurakevych, Oleksandr O., Solozhenko, Vladimir L.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: MDPI 2016
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6273604/
https://www.ncbi.nlm.nih.gov/pubmed/27775629
http://dx.doi.org/10.3390/molecules21101399
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author Kurakevych, Oleksandr O.
Solozhenko, Vladimir L.
author_facet Kurakevych, Oleksandr O.
Solozhenko, Vladimir L.
author_sort Kurakevych, Oleksandr O.
collection PubMed
description The aim of the present review is to highlight the state of the art in high-pressure design of new advanced materials based on boron nitride. Recent experimental achievements on the governing phase transformation, nanostructuring and chemical synthesis in the systems containing boron nitride at high pressures and high temperatures are presented. All these developments allowed discovering new materials, e.g., ultrahard nanocrystalline cubic boron nitride (nano-cBN) with hardness comparable to diamond, and superhard boron subnitride B(13)N(2). Thermodynamic and kinetic aspects of high-pressure synthesis are described based on the data obtained by in situ and ex situ methods. Mechanical and thermal properties (hardness, thermoelastic equations of state, etc.) are discussed. New synthetic perspectives, combining both soft chemistry and extreme pressure–temperature conditions are considered.
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spelling pubmed-62736042018-12-28 High-Pressure Design of Advanced BN-Based Materials Kurakevych, Oleksandr O. Solozhenko, Vladimir L. Molecules Review The aim of the present review is to highlight the state of the art in high-pressure design of new advanced materials based on boron nitride. Recent experimental achievements on the governing phase transformation, nanostructuring and chemical synthesis in the systems containing boron nitride at high pressures and high temperatures are presented. All these developments allowed discovering new materials, e.g., ultrahard nanocrystalline cubic boron nitride (nano-cBN) with hardness comparable to diamond, and superhard boron subnitride B(13)N(2). Thermodynamic and kinetic aspects of high-pressure synthesis are described based on the data obtained by in situ and ex situ methods. Mechanical and thermal properties (hardness, thermoelastic equations of state, etc.) are discussed. New synthetic perspectives, combining both soft chemistry and extreme pressure–temperature conditions are considered. MDPI 2016-10-20 /pmc/articles/PMC6273604/ /pubmed/27775629 http://dx.doi.org/10.3390/molecules21101399 Text en © 2016 by the authors. Licensee MDPI, Basel, Switzerland. This article is an open access article distributed under the terms and conditions of the Creative Commons Attribution (CC-BY) license (http://creativecommons.org/licenses/by/4.0/).
spellingShingle Review
Kurakevych, Oleksandr O.
Solozhenko, Vladimir L.
High-Pressure Design of Advanced BN-Based Materials
title High-Pressure Design of Advanced BN-Based Materials
title_full High-Pressure Design of Advanced BN-Based Materials
title_fullStr High-Pressure Design of Advanced BN-Based Materials
title_full_unstemmed High-Pressure Design of Advanced BN-Based Materials
title_short High-Pressure Design of Advanced BN-Based Materials
title_sort high-pressure design of advanced bn-based materials
topic Review
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6273604/
https://www.ncbi.nlm.nih.gov/pubmed/27775629
http://dx.doi.org/10.3390/molecules21101399
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