Palladium(II) Catalyzed Cyclization-Carbonylation-Cyclization Coupling Reaction of (ortho-Alkynyl Phenyl) (Methoxymethyl) Sulfides Using Molecular Oxygen as the Terminal Oxidant

An efficient Pd(II)/Pd(0)-p-benzoquinone/hydroquinone-CuCl(2)/CuCl catalyst system was developed that uses environmentally friendly molecular oxygen as the terminal oxidant to catalyze the cyclization-carbonylation-cyclization coupling reaction (CCC-coupling reaction) of (o-alkynyl phenyl) (methoxym...

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Autores principales: Shen, Rong, Kusakabe, Taichi, Yatsu, Tomofumi, Kanno, Yuichiro, Takahashi, Keisuke, Nemoto, Kiyomitsu, Kato, Keisuke
Formato: Online Artículo Texto
Lenguaje:English
Publicado: MDPI 2016
Materias:
Article
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6273608/
https://www.ncbi.nlm.nih.gov/pubmed/27607997
http://dx.doi.org/10.3390/molecules21091177
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author Shen, Rong
Kusakabe, Taichi
Yatsu, Tomofumi
Kanno, Yuichiro
Takahashi, Keisuke
Nemoto, Kiyomitsu
Kato, Keisuke
author_facet Shen, Rong
Kusakabe, Taichi
Yatsu, Tomofumi
Kanno, Yuichiro
Takahashi, Keisuke
Nemoto, Kiyomitsu
Kato, Keisuke
author_sort Shen, Rong
collection PubMed
description An efficient Pd(II)/Pd(0)-p-benzoquinone/hydroquinone-CuCl(2)/CuCl catalyst system was developed that uses environmentally friendly molecular oxygen as the terminal oxidant to catalyze the cyclization-carbonylation-cyclization coupling reaction (CCC-coupling reaction) of (o-alkynyl phenyl) (methoxymethyl) sulfides.
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spelling pubmed-62736082018-12-28 Palladium(II) Catalyzed Cyclization-Carbonylation-Cyclization Coupling Reaction of (ortho-Alkynyl Phenyl) (Methoxymethyl) Sulfides Using Molecular Oxygen as the Terminal Oxidant Shen, Rong Kusakabe, Taichi Yatsu, Tomofumi Kanno, Yuichiro Takahashi, Keisuke Nemoto, Kiyomitsu Kato, Keisuke Molecules Article An efficient Pd(II)/Pd(0)-p-benzoquinone/hydroquinone-CuCl(2)/CuCl catalyst system was developed that uses environmentally friendly molecular oxygen as the terminal oxidant to catalyze the cyclization-carbonylation-cyclization coupling reaction (CCC-coupling reaction) of (o-alkynyl phenyl) (methoxymethyl) sulfides. MDPI 2016-09-05 /pmc/articles/PMC6273608/ /pubmed/27607997 http://dx.doi.org/10.3390/molecules21091177 Text en © 2016 by the authors. Licensee MDPI, Basel, Switzerland. This article is an open access article distributed under the terms and conditions of the Creative Commons Attribution (CC-BY) license (http://creativecommons.org/licenses/by/4.0/).
spellingShingle Article
Shen, Rong
Kusakabe, Taichi
Yatsu, Tomofumi
Kanno, Yuichiro
Takahashi, Keisuke
Nemoto, Kiyomitsu
Kato, Keisuke
Palladium(II) Catalyzed Cyclization-Carbonylation-Cyclization Coupling Reaction of (ortho-Alkynyl Phenyl) (Methoxymethyl) Sulfides Using Molecular Oxygen as the Terminal Oxidant
title Palladium(II) Catalyzed Cyclization-Carbonylation-Cyclization Coupling Reaction of (ortho-Alkynyl Phenyl) (Methoxymethyl) Sulfides Using Molecular Oxygen as the Terminal Oxidant
title_full Palladium(II) Catalyzed Cyclization-Carbonylation-Cyclization Coupling Reaction of (ortho-Alkynyl Phenyl) (Methoxymethyl) Sulfides Using Molecular Oxygen as the Terminal Oxidant
title_fullStr Palladium(II) Catalyzed Cyclization-Carbonylation-Cyclization Coupling Reaction of (ortho-Alkynyl Phenyl) (Methoxymethyl) Sulfides Using Molecular Oxygen as the Terminal Oxidant
title_full_unstemmed Palladium(II) Catalyzed Cyclization-Carbonylation-Cyclization Coupling Reaction of (ortho-Alkynyl Phenyl) (Methoxymethyl) Sulfides Using Molecular Oxygen as the Terminal Oxidant
title_short Palladium(II) Catalyzed Cyclization-Carbonylation-Cyclization Coupling Reaction of (ortho-Alkynyl Phenyl) (Methoxymethyl) Sulfides Using Molecular Oxygen as the Terminal Oxidant
title_sort palladium(ii) catalyzed cyclization-carbonylation-cyclization coupling reaction of (ortho-alkynyl phenyl) (methoxymethyl) sulfides using molecular oxygen as the terminal oxidant
topic Article
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6273608/
https://www.ncbi.nlm.nih.gov/pubmed/27607997
http://dx.doi.org/10.3390/molecules21091177
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