Heterogeneous Phase Microwave-Assisted Reactions under CO(2) or CO Pressure

The present review deals with the recent achievements and impressive potential applications of microwave (MW) heating to promote heterogeneous reactions under gas pressure. The high versatility of the latest generation of professional reactors combines extreme reaction conditions with safer and more...

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Detalles Bibliográficos
Autores principales: Calcio Gaudino, Emanuela, Rinaldi, Laura, Rotolo, Laura, Carnaroglio, Diego, Pirola, Camillo, Cravotto, Giancarlo
Formato: Online Artículo Texto
Lenguaje:English
Publicado: MDPI 2016
Materias:
Review
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6273686/
https://www.ncbi.nlm.nih.gov/pubmed/26927033
http://dx.doi.org/10.3390/molecules21030253
Descripción
Sumario:The present review deals with the recent achievements and impressive potential applications of microwave (MW) heating to promote heterogeneous reactions under gas pressure. The high versatility of the latest generation of professional reactors combines extreme reaction conditions with safer and more efficient protocols. The double aims of this survey are to provide a panoramic snapshot of MW-assisted organic reactions with gaseous reagents, in particular CO and CO(2), and outline future applications. Stubborn and time-consuming carbonylation-like heterogeneous reactions, which have not yet been studied under dielectric heating, may well find an outstanding ally in the present protocol.

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