Heterogeneous Phase Microwave-Assisted Reactions under CO(2) or CO Pressure

The present review deals with the recent achievements and impressive potential applications of microwave (MW) heating to promote heterogeneous reactions under gas pressure. The high versatility of the latest generation of professional reactors combines extreme reaction conditions with safer and more...

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Autores principales: Calcio Gaudino, Emanuela, Rinaldi, Laura, Rotolo, Laura, Carnaroglio, Diego, Pirola, Camillo, Cravotto, Giancarlo
Formato: Online Artículo Texto
Lenguaje:English
Publicado: MDPI 2016
Materias:
Review
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6273686/
https://www.ncbi.nlm.nih.gov/pubmed/26927033
http://dx.doi.org/10.3390/molecules21030253
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author Calcio Gaudino, Emanuela
Rinaldi, Laura
Rotolo, Laura
Carnaroglio, Diego
Pirola, Camillo
Cravotto, Giancarlo
author_facet Calcio Gaudino, Emanuela
Rinaldi, Laura
Rotolo, Laura
Carnaroglio, Diego
Pirola, Camillo
Cravotto, Giancarlo
author_sort Calcio Gaudino, Emanuela
collection PubMed
description The present review deals with the recent achievements and impressive potential applications of microwave (MW) heating to promote heterogeneous reactions under gas pressure. The high versatility of the latest generation of professional reactors combines extreme reaction conditions with safer and more efficient protocols. The double aims of this survey are to provide a panoramic snapshot of MW-assisted organic reactions with gaseous reagents, in particular CO and CO(2), and outline future applications. Stubborn and time-consuming carbonylation-like heterogeneous reactions, which have not yet been studied under dielectric heating, may well find an outstanding ally in the present protocol.
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spelling pubmed-62736862018-12-28 Heterogeneous Phase Microwave-Assisted Reactions under CO(2) or CO Pressure Calcio Gaudino, Emanuela Rinaldi, Laura Rotolo, Laura Carnaroglio, Diego Pirola, Camillo Cravotto, Giancarlo Molecules Review The present review deals with the recent achievements and impressive potential applications of microwave (MW) heating to promote heterogeneous reactions under gas pressure. The high versatility of the latest generation of professional reactors combines extreme reaction conditions with safer and more efficient protocols. The double aims of this survey are to provide a panoramic snapshot of MW-assisted organic reactions with gaseous reagents, in particular CO and CO(2), and outline future applications. Stubborn and time-consuming carbonylation-like heterogeneous reactions, which have not yet been studied under dielectric heating, may well find an outstanding ally in the present protocol. MDPI 2016-02-24 /pmc/articles/PMC6273686/ /pubmed/26927033 http://dx.doi.org/10.3390/molecules21030253 Text en © 2016 by the authors. Licensee MDPI, Basel, Switzerland. This article is an open access article distributed under the terms and conditions of the Creative Commons by Attribution (CC-BY) license (http://creativecommons.org/licenses/by/4.0/).
spellingShingle Review
Calcio Gaudino, Emanuela
Rinaldi, Laura
Rotolo, Laura
Carnaroglio, Diego
Pirola, Camillo
Cravotto, Giancarlo
Heterogeneous Phase Microwave-Assisted Reactions under CO(2) or CO Pressure
title Heterogeneous Phase Microwave-Assisted Reactions under CO(2) or CO Pressure
title_full Heterogeneous Phase Microwave-Assisted Reactions under CO(2) or CO Pressure
title_fullStr Heterogeneous Phase Microwave-Assisted Reactions under CO(2) or CO Pressure
title_full_unstemmed Heterogeneous Phase Microwave-Assisted Reactions under CO(2) or CO Pressure
title_short Heterogeneous Phase Microwave-Assisted Reactions under CO(2) or CO Pressure
title_sort heterogeneous phase microwave-assisted reactions under co(2) or co pressure
topic Review
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6273686/
https://www.ncbi.nlm.nih.gov/pubmed/26927033
http://dx.doi.org/10.3390/molecules21030253
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