Radical Smiles Rearrangement: An Update

Over the decades the Smiles rearrangement and its variants have become essential synthetic tools in modern synthetic organic chemistry. In this mini-review we summarized some very recent results of the radical version of these rearrangements. The selected examples illustrate the synthetic power of t...

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Detalles Bibliográficos
Autores principales: Allart-Simon, Ingrid, Gérard, Stéphane, Sapi, Janos
Formato: Online Artículo Texto
Lenguaje:English
Publicado: MDPI 2016
Materias:
Review
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6273782/
https://www.ncbi.nlm.nih.gov/pubmed/27399654
http://dx.doi.org/10.3390/molecules21070878
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author Allart-Simon, Ingrid
Gérard, Stéphane
Sapi, Janos
author_facet Allart-Simon, Ingrid
Gérard, Stéphane
Sapi, Janos
author_sort Allart-Simon, Ingrid
collection PubMed
description Over the decades the Smiles rearrangement and its variants have become essential synthetic tools in modern synthetic organic chemistry. In this mini-review we summarized some very recent results of the radical version of these rearrangements. The selected examples illustrate the synthetic power of this approach, especially if it is incorporated into a domino process, for the preparation of polyfunctionalized complex molecules.
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spelling pubmed-62737822018-12-28 Radical Smiles Rearrangement: An Update Allart-Simon, Ingrid Gérard, Stéphane Sapi, Janos Molecules Review Over the decades the Smiles rearrangement and its variants have become essential synthetic tools in modern synthetic organic chemistry. In this mini-review we summarized some very recent results of the radical version of these rearrangements. The selected examples illustrate the synthetic power of this approach, especially if it is incorporated into a domino process, for the preparation of polyfunctionalized complex molecules. MDPI 2016-07-06 /pmc/articles/PMC6273782/ /pubmed/27399654 http://dx.doi.org/10.3390/molecules21070878 Text en © 2016 by the authors. Licensee MDPI, Basel, Switzerland. This article is an open access article distributed under the terms and conditions of the Creative Commons Attribution (CC-BY) license (http://creativecommons.org/licenses/by/4.0/).
spellingShingle Review
Allart-Simon, Ingrid
Gérard, Stéphane
Sapi, Janos
Radical Smiles Rearrangement: An Update
title Radical Smiles Rearrangement: An Update
title_full Radical Smiles Rearrangement: An Update
title_fullStr Radical Smiles Rearrangement: An Update
title_full_unstemmed Radical Smiles Rearrangement: An Update
title_short Radical Smiles Rearrangement: An Update
title_sort radical smiles rearrangement: an update
topic Review
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6273782/
https://www.ncbi.nlm.nih.gov/pubmed/27399654
http://dx.doi.org/10.3390/molecules21070878
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AT gerardstephane radicalsmilesrearrangementanupdate
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