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Biogenesis of Triterpene Dimers from Orthoquinones Related to Quinonemethides: Theoretical Study on the Reaction Mechanism

The biogenetic origin of triterpene dimers from the Celastraceae family has been proposed as assisted hetero-Diels-Alder reaction (HDA). In this work, computational calculation of HDA between natural quinonemethides (tingenone and isopristimerol) and hypothetical orthoquinones has been performed at...

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Detalles Bibliográficos
Autores principales: Quesadas-Rojas, Mariana, Mena-Rejón, Gonzalo J., Cáceres-Castillo, David, Cuevas, Gabriel, Quijano-Quiñones, Ramiro F.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: MDPI 2016
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6273858/
https://www.ncbi.nlm.nih.gov/pubmed/27869690
http://dx.doi.org/10.3390/molecules21111551