Spectroscopic and Kinetic Characterization of Peroxidase-Like π-Cation Radical Pinch-Porphyrin-Iron(III) Reaction Intermediate Models of Peroxidase Enzymes

The spectroscopic and kinetic characterization of two intermediates from the H(2)O(2) oxidation of three dimethyl ester [(proto), (meso), (deuteroporphyrinato) (picdien)]Fe(III) complexes ([FePPPic], [FeMPPic] and [FeDPPic], respectively) pinch-porphyrin peroxidase enzyme models, with s = 5/2 and 3/...

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Detalles Bibliográficos
Autores principales: Hernández Anzaldo, Samuel, Arroyo Abad, Uriel, León García, Armando, Ramírez Rosales, Daniel, Zamorano Ulloa, Rafael, Reyes Ortega, Yasmi
Formato: Online Artículo Texto
Lenguaje:English
Publicado: MDPI 2016
Materias:
Article
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6273987/
https://www.ncbi.nlm.nih.gov/pubmed/27355940
http://dx.doi.org/10.3390/molecules21070804

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