NHC Backbone Configuration in Ruthenium-Catalyzed Olefin Metathesis

The catalytic properties of olefin metathesis ruthenium complexes bearing N-heterocyclic carbene ligands with stereogenic centers on the backbone are described. Differences in catalytic behavior depending on the backbone configurations of symmetrical and unsymmetrical NHCs are discussed. In addition...

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Detalles Bibliográficos
Autores principales: Paradiso, Veronica, Costabile, Chiara, Grisi, Fabia
Formato: Online Artículo Texto
Lenguaje:English
Publicado: MDPI 2016
Materias:
Review
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6274038/
https://www.ncbi.nlm.nih.gov/pubmed/26805793
http://dx.doi.org/10.3390/molecules21010117
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author Paradiso, Veronica
Costabile, Chiara
Grisi, Fabia
author_facet Paradiso, Veronica
Costabile, Chiara
Grisi, Fabia
author_sort Paradiso, Veronica
collection PubMed
description The catalytic properties of olefin metathesis ruthenium complexes bearing N-heterocyclic carbene ligands with stereogenic centers on the backbone are described. Differences in catalytic behavior depending on the backbone configurations of symmetrical and unsymmetrical NHCs are discussed. In addition, an overview on asymmetric olefin metathesis promoted by chiral catalysts bearing C(2)-symmetric and C(1)-symmetric NHCs is provided.
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spelling pubmed-62740382018-12-28 NHC Backbone Configuration in Ruthenium-Catalyzed Olefin Metathesis Paradiso, Veronica Costabile, Chiara Grisi, Fabia Molecules Review The catalytic properties of olefin metathesis ruthenium complexes bearing N-heterocyclic carbene ligands with stereogenic centers on the backbone are described. Differences in catalytic behavior depending on the backbone configurations of symmetrical and unsymmetrical NHCs are discussed. In addition, an overview on asymmetric olefin metathesis promoted by chiral catalysts bearing C(2)-symmetric and C(1)-symmetric NHCs is provided. MDPI 2016-01-20 /pmc/articles/PMC6274038/ /pubmed/26805793 http://dx.doi.org/10.3390/molecules21010117 Text en © 2016 by the authors. Licensee MDPI, Basel, Switzerland. This article is an open access article distributed under the terms and conditions of the Creative Commons by Attribution (CC-BY) license (http://creativecommons.org/licenses/by/4.0/).
spellingShingle Review
Paradiso, Veronica
Costabile, Chiara
Grisi, Fabia
NHC Backbone Configuration in Ruthenium-Catalyzed Olefin Metathesis
title NHC Backbone Configuration in Ruthenium-Catalyzed Olefin Metathesis
title_full NHC Backbone Configuration in Ruthenium-Catalyzed Olefin Metathesis
title_fullStr NHC Backbone Configuration in Ruthenium-Catalyzed Olefin Metathesis
title_full_unstemmed NHC Backbone Configuration in Ruthenium-Catalyzed Olefin Metathesis
title_short NHC Backbone Configuration in Ruthenium-Catalyzed Olefin Metathesis
title_sort nhc backbone configuration in ruthenium-catalyzed olefin metathesis
topic Review
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6274038/
https://www.ncbi.nlm.nih.gov/pubmed/26805793
http://dx.doi.org/10.3390/molecules21010117
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AT costabilechiara nhcbackboneconfigurationinrutheniumcatalyzedolefinmetathesis
AT grisifabia nhcbackboneconfigurationinrutheniumcatalyzedolefinmetathesis

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