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A Well-Defined {[(PhCH(2)O)(2)P(CH(3))(2)CHNCH(CH(3))(2)](2)PdCl(2)} Complex Catalyzed Hiyama Coupling of Aryl Bromides with Arylsilanes
A palladium (II) complex {[(PhCH(2)O)(2)P(CH(3))(2)CHNCH(CH(3))(2)](2)PdCl(2)} catalyzed Hiyama cross-coupling reaction between aryl bromides and arylsilanes has been developed. The substituted biaryls were produced in moderate to high yields, regardless of electron-withdrawing or electron-donating....
Autores principales: | , , , , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
MDPI
2016
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6274572/ https://www.ncbi.nlm.nih.gov/pubmed/27483226 http://dx.doi.org/10.3390/molecules21080987 |
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author | Guo, Mengping Fu, Leiqing Li, Jiamin Zhou, Lanjiang Kang, Yanping |
author_facet | Guo, Mengping Fu, Leiqing Li, Jiamin Zhou, Lanjiang Kang, Yanping |
author_sort | Guo, Mengping |
collection | PubMed |
description | A palladium (II) complex {[(PhCH(2)O)(2)P(CH(3))(2)CHNCH(CH(3))(2)](2)PdCl(2)} catalyzed Hiyama cross-coupling reaction between aryl bromides and arylsilanes has been developed. The substituted biaryls were produced in moderate to high yields, regardless of electron-withdrawing or electron-donating. [Image: see text] |
format | Online Article Text |
id | pubmed-6274572 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2016 |
publisher | MDPI |
record_format | MEDLINE/PubMed |
spelling | pubmed-62745722018-12-28 A Well-Defined {[(PhCH(2)O)(2)P(CH(3))(2)CHNCH(CH(3))(2)](2)PdCl(2)} Complex Catalyzed Hiyama Coupling of Aryl Bromides with Arylsilanes Guo, Mengping Fu, Leiqing Li, Jiamin Zhou, Lanjiang Kang, Yanping Molecules Article A palladium (II) complex {[(PhCH(2)O)(2)P(CH(3))(2)CHNCH(CH(3))(2)](2)PdCl(2)} catalyzed Hiyama cross-coupling reaction between aryl bromides and arylsilanes has been developed. The substituted biaryls were produced in moderate to high yields, regardless of electron-withdrawing or electron-donating. [Image: see text] MDPI 2016-07-29 /pmc/articles/PMC6274572/ /pubmed/27483226 http://dx.doi.org/10.3390/molecules21080987 Text en © 2016 by the authors. Licensee MDPI, Basel, Switzerland. This article is an open access article distributed under the terms and conditions of the Creative Commons Attribution (CC-BY) license (http://creativecommons.org/licenses/by/4.0/). |
spellingShingle | Article Guo, Mengping Fu, Leiqing Li, Jiamin Zhou, Lanjiang Kang, Yanping A Well-Defined {[(PhCH(2)O)(2)P(CH(3))(2)CHNCH(CH(3))(2)](2)PdCl(2)} Complex Catalyzed Hiyama Coupling of Aryl Bromides with Arylsilanes |
title | A Well-Defined {[(PhCH(2)O)(2)P(CH(3))(2)CHNCH(CH(3))(2)](2)PdCl(2)} Complex Catalyzed Hiyama Coupling of Aryl Bromides with Arylsilanes |
title_full | A Well-Defined {[(PhCH(2)O)(2)P(CH(3))(2)CHNCH(CH(3))(2)](2)PdCl(2)} Complex Catalyzed Hiyama Coupling of Aryl Bromides with Arylsilanes |
title_fullStr | A Well-Defined {[(PhCH(2)O)(2)P(CH(3))(2)CHNCH(CH(3))(2)](2)PdCl(2)} Complex Catalyzed Hiyama Coupling of Aryl Bromides with Arylsilanes |
title_full_unstemmed | A Well-Defined {[(PhCH(2)O)(2)P(CH(3))(2)CHNCH(CH(3))(2)](2)PdCl(2)} Complex Catalyzed Hiyama Coupling of Aryl Bromides with Arylsilanes |
title_short | A Well-Defined {[(PhCH(2)O)(2)P(CH(3))(2)CHNCH(CH(3))(2)](2)PdCl(2)} Complex Catalyzed Hiyama Coupling of Aryl Bromides with Arylsilanes |
title_sort | well-defined {[(phch(2)o)(2)p(ch(3))(2)chnch(ch(3))(2)](2)pdcl(2)} complex catalyzed hiyama coupling of aryl bromides with arylsilanes |
topic | Article |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6274572/ https://www.ncbi.nlm.nih.gov/pubmed/27483226 http://dx.doi.org/10.3390/molecules21080987 |
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