Better Resolution of High-Spin Cobalt Hyperfine at Low Frequency: Co-Doped Ba(Zn(1/3)Ta(2/3))O(3) as a Model Complex

Low-frequency electron paramagnetic resonance (EPR) is used to extract the EPR parameter A-mid and support the approximate X-band value of g-mid for Ba(Co(y)Zn(1/3−y)Ta(2/3))O(3). Although the cobalt hyperfine structure for the |±1/2〉 state is often unresolved at X-band or S-band, it is resolved in...

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Detalles Bibliográficos
Autores principales: Antholine, William E., Zhang, Shengke, Gonzales, Justin, Newman, Nathan
Formato: Online Artículo Texto
Lenguaje:English
Publicado: MDPI 2018
Materias:
Communication
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6274703/
https://www.ncbi.nlm.nih.gov/pubmed/30423944
http://dx.doi.org/10.3390/ijms19113532
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author Antholine, William E.
Zhang, Shengke
Gonzales, Justin
Newman, Nathan
author_facet Antholine, William E.
Zhang, Shengke
Gonzales, Justin
Newman, Nathan
author_sort Antholine, William E.
collection PubMed
description Low-frequency electron paramagnetic resonance (EPR) is used to extract the EPR parameter A-mid and support the approximate X-band value of g-mid for Ba(Co(y)Zn(1/3−y)Ta(2/3))O(3). Although the cobalt hyperfine structure for the |±1/2〉 state is often unresolved at X-band or S-band, it is resolved in measurements on this compound. This allows for detailed analysis of the molecular orbital for the |±1/2〉 state, which is often the ground state. Moreover, this work shows that the EPR parameters for Co substituted into Zn compounds give important insight into the properties of zinc binding sites.
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spelling pubmed-62747032018-12-15 Better Resolution of High-Spin Cobalt Hyperfine at Low Frequency: Co-Doped Ba(Zn(1/3)Ta(2/3))O(3) as a Model Complex Antholine, William E. Zhang, Shengke Gonzales, Justin Newman, Nathan Int J Mol Sci Communication Low-frequency electron paramagnetic resonance (EPR) is used to extract the EPR parameter A-mid and support the approximate X-band value of g-mid for Ba(Co(y)Zn(1/3−y)Ta(2/3))O(3). Although the cobalt hyperfine structure for the |±1/2〉 state is often unresolved at X-band or S-band, it is resolved in measurements on this compound. This allows for detailed analysis of the molecular orbital for the |±1/2〉 state, which is often the ground state. Moreover, this work shows that the EPR parameters for Co substituted into Zn compounds give important insight into the properties of zinc binding sites. MDPI 2018-11-09 /pmc/articles/PMC6274703/ /pubmed/30423944 http://dx.doi.org/10.3390/ijms19113532 Text en © 2018 by the authors. Licensee MDPI, Basel, Switzerland. This article is an open access article distributed under the terms and conditions of the Creative Commons Attribution (CC BY) license (http://creativecommons.org/licenses/by/4.0/).
spellingShingle Communication
Antholine, William E.
Zhang, Shengke
Gonzales, Justin
Newman, Nathan
Better Resolution of High-Spin Cobalt Hyperfine at Low Frequency: Co-Doped Ba(Zn(1/3)Ta(2/3))O(3) as a Model Complex
title Better Resolution of High-Spin Cobalt Hyperfine at Low Frequency: Co-Doped Ba(Zn(1/3)Ta(2/3))O(3) as a Model Complex
title_full Better Resolution of High-Spin Cobalt Hyperfine at Low Frequency: Co-Doped Ba(Zn(1/3)Ta(2/3))O(3) as a Model Complex
title_fullStr Better Resolution of High-Spin Cobalt Hyperfine at Low Frequency: Co-Doped Ba(Zn(1/3)Ta(2/3))O(3) as a Model Complex
title_full_unstemmed Better Resolution of High-Spin Cobalt Hyperfine at Low Frequency: Co-Doped Ba(Zn(1/3)Ta(2/3))O(3) as a Model Complex
title_short Better Resolution of High-Spin Cobalt Hyperfine at Low Frequency: Co-Doped Ba(Zn(1/3)Ta(2/3))O(3) as a Model Complex
title_sort better resolution of high-spin cobalt hyperfine at low frequency: co-doped ba(zn(1/3)ta(2/3))o(3) as a model complex
topic Communication
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6274703/
https://www.ncbi.nlm.nih.gov/pubmed/30423944
http://dx.doi.org/10.3390/ijms19113532
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