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Reaction between Indazole and Pd-Bound Isocyanides—A Theoretical Mechanistic Study

The mechanism of the addition of indazole (Ind)—a bifunctional aromatic N,NH-nucleophile—to cyclohexyl isocyanide coordinated to the palladium(II) center in the model complex cis-[PdCl(2)(CNMe)(CNCy)] (1) to give the corresponding aminocarbene ligand was investigated in detail by theoretical (DFT) m...

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Detalles Bibliográficos
Autores principales: Casella, Girolamo, Casarin, Maurizio, Kukushkin, Vadim Yu., Kuznetsov, Maxim L.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: MDPI 2018
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6278333/
https://www.ncbi.nlm.nih.gov/pubmed/30423833
http://dx.doi.org/10.3390/molecules23112942

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