Bis(6-Diphenylphosphinoacenaphth-5-yl)Telluride as a Ligand toward Manganese and Rhenium Carbonyls

The reaction of the previously known bis(6-diphenylphosphinoacenaphthyl-5-)telluride (6-Ph(2)P-Ace-5-)(2)Te (IV) with (CO)(5)ReCl and (CO)(5)MnBr proceeded with the liberation of CO and provided fac-(6-Ph(2)P-Ace-5-)(2)TeM(X)(CO)(3) (fac-1: M = Re, X = Cl; fac-2: M = Mn, X = Br), in which IV acts as...

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Detalles Bibliográficos
Autores principales: Do, Truong Giang, Hupf, Emanuel, Lork, Enno, Beckmann, Jens
Formato: Online Artículo Texto
Lenguaje:English
Publicado: MDPI 2018
Materias:
Article
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6278489/
https://www.ncbi.nlm.nih.gov/pubmed/30380637
http://dx.doi.org/10.3390/molecules23112805
Descripción
Sumario:The reaction of the previously known bis(6-diphenylphosphinoacenaphthyl-5-)telluride (6-Ph(2)P-Ace-5-)(2)Te (IV) with (CO)(5)ReCl and (CO)(5)MnBr proceeded with the liberation of CO and provided fac-(6-Ph(2)P-Ace-5-)(2)TeM(X)(CO)(3) (fac-1: M = Re, X = Cl; fac-2: M = Mn, X = Br), in which IV acts as bidentate ligand. In solution, fac-1 and fac-2 are engaged in a reversible equilibrium with mer-(6-Ph(2)P-Ace-5-)(2)TeM(X)(CO)(3) (mer-1: M = Re, X = Cl; mer-2: M = Mn, X = Br). Unlike fac-1, fac-2 is prone to release another equivalent of CO to give (6-Ph(2)P-Ace-5-)(2)TeMn(Br)(CO)(2) (3), in which IV serves as tridentate ligand.

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